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<!--XBRL Document Created with the Workiva Platform-->
<!--Copyright 2026 Workiva-->
<!--r:01a0c4ac-2d25-7f69-8a04-5d8971a013ab,g:59f81940-8961-4d2b-b415-8dac5822c11a-->
<xs:schema xmlns:xs="http://www.w3.org/2001/XMLSchema" xmlns:link="http://www.xbrl.org/2003/linkbase" xmlns:et="http://www.energytransfer.com/20251231" xmlns:xbrli="http://www.xbrl.org/2003/instance" xmlns:dtr-types="http://www.xbrl.org/dtr/type/2024-01-31" attributeFormDefault="unqualified" elementFormDefault="qualified" targetNamespace="http://www.energytransfer.com/20251231">
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  <xs:import namespace="http://www.xbrl.org/2003/linkbase" schemaLocation="http://www.xbrl.org/2003/xbrl-linkbase-2003-12-31.xsd"/>
  <xs:import namespace="http://www.xbrl.org/dtr/type/2024-01-31" schemaLocation="https://www.xbrl.org/dtr/type/2024-01-31/types.xsd"/>
  <xs:import namespace="http://xbrl.sec.gov/country/2026" schemaLocation="https://xbrl.sec.gov/country/2026/country-2026.xsd"/>
  <xs:import namespace="http://xbrl.sec.gov/dei/2026" schemaLocation="https://xbrl.sec.gov/dei/2026/dei-2026.xsd"/>
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        <link:roleRef roleURI="http://xbrl.sec.gov/rxp/role/ByGovernment" xlink:type="simple" xlink:href="https://xbrl.sec.gov/rxp/2026/rxp-2026.xsd#ByGovernment"/>
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        <link:roleRef roleURI="http://www.xbrl.org/2009/role/negatedTerseLabel" xlink:type="simple" xlink:href="http://www.xbrl.org/lrr/role/negated-2009-12-16.xsd#negatedTerseLabel"/>
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        <link:roleRef roleURI="http://www.xbrl.org/2009/role/negatedTotalLabel" xlink:type="simple" xlink:href="http://www.xbrl.org/lrr/role/negated-2009-12-16.xsd#negatedTotalLabel"/>
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          <link:label id="lab_et_UnitedStatesFederalGovernmentMember_label_en-US" xlink:label="lab_et_UnitedStatesFederalGovernmentMember" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en-US">United States Federal Government [Member]</link:label>
          <link:loc xlink:type="locator" xlink:label="loc_et_UnitedStatesFederalGovernmentMember" xlink:href="et-20251231.xsd#et_UnitedStatesFederalGovernmentMember"/>
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          <link:loc xlink:type="locator" xlink:label="loc_et_OilAndNaturalGasMember" xlink:href="et-20251231.xsd#et_OilAndNaturalGasMember"/>
          <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_et_OilAndNaturalGasMember" xlink:to="lab_et_OilAndNaturalGasMember" xlink:type="arc" order="1"/>
        </link:labelLink>
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  <xs:element id="et_UnitedStatesFederalGovernmentMember" abstract="true" name="UnitedStatesFederalGovernmentMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="et_OilAndNaturalGasMember" abstract="true" name="OilAndNaturalGasMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
</xs:schema>
