<?xml version="1.0" encoding="utf-8"?>
<!--XBRL document created with Toppan Merrill Bridge  11.4.0.1 -->
<!--Based on XBRL 2.1-->
<!--Created on: 9/21/2026 1:13:18 PM-->
<!--Modified on: 9/21/2026 1:13:18 PM-->
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        <link:labelLink xlink:type="extended" xlink:role="http://www.xbrl.org/2003/role/link">
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          <labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="cmcl_BlanketMineProjectMember" xlink:to="cmcl_BlanketMineProjectMember_lbl" xmlns="http://www.xbrl.org/2003/linkbase" />
          <label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:label="cmcl_BlanketMineProjectMember_lbl" xml:lang="en-US" xmlns="http://www.xbrl.org/2003/linkbase">This member stands for the project of Blanket Mine.</label>
          <label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/label" xlink:label="cmcl_BlanketMineProjectMember_lbl" xml:lang="en-US" xmlns="http://www.xbrl.org/2003/linkbase">Blanket Mine Project [Member]</label>
          <label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/terseLabel" xlink:label="cmcl_BlanketMineProjectMember_lbl" xml:lang="en-US" xmlns="http://www.xbrl.org/2003/linkbase">Blanket Mine</label>
          <loc xlink:type="locator" xlink:href="#cmcl_CaledoniaHoldingsZimbabwePrivateLimitedProjectMember" xlink:label="cmcl_CaledoniaHoldingsZimbabwePrivateLimitedProjectMember" xmlns="http://www.xbrl.org/2003/linkbase" />
          <labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="cmcl_CaledoniaHoldingsZimbabwePrivateLimitedProjectMember" xlink:to="cmcl_CaledoniaHoldingsZimbabwePrivateLimitedProjectMember_lbl" xmlns="http://www.xbrl.org/2003/linkbase" />
          <label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:label="cmcl_CaledoniaHoldingsZimbabwePrivateLimitedProjectMember_lbl" xml:lang="en-US" xmlns="http://www.xbrl.org/2003/linkbase">This member stands for the project of Caledonia Holdings Zimbabwe (Private) Limited.</label>
          <label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/label" xlink:label="cmcl_CaledoniaHoldingsZimbabwePrivateLimitedProjectMember_lbl" xml:lang="en-US" xmlns="http://www.xbrl.org/2003/linkbase">Caledonia Holdings Zimbabwe (Private) Limited Project [Member]</label>
          <label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/terseLabel" xlink:label="cmcl_CaledoniaHoldingsZimbabwePrivateLimitedProjectMember_lbl" xml:lang="en-US" xmlns="http://www.xbrl.org/2003/linkbase">Caledonia Holdings Zimbabwe (Private) Limited</label>
          <loc xlink:type="locator" xlink:href="#cmcl_BilboesOxideMineProjectMember" xlink:label="cmcl_BilboesOxideMineProjectMember" xmlns="http://www.xbrl.org/2003/linkbase" />
          <labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="cmcl_BilboesOxideMineProjectMember" xlink:to="cmcl_BilboesOxideMineProjectMember_lbl" xmlns="http://www.xbrl.org/2003/linkbase" />
          <label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:label="cmcl_BilboesOxideMineProjectMember_lbl" xml:lang="en-US" xmlns="http://www.xbrl.org/2003/linkbase">This member stands for the project of Bilboes (Oxide mine).</label>
          <label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/label" xlink:label="cmcl_BilboesOxideMineProjectMember_lbl" xml:lang="en-US" xmlns="http://www.xbrl.org/2003/linkbase">Bilboes (Oxide mine) Project [Member]</label>
          <label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/terseLabel" xlink:label="cmcl_BilboesOxideMineProjectMember_lbl" xml:lang="en-US" xmlns="http://www.xbrl.org/2003/linkbase">Bilboes (Oxide mine)</label>
          <loc xlink:type="locator" xlink:href="#cmcl_MotapaProjectMember" xlink:label="cmcl_MotapaProjectMember" xmlns="http://www.xbrl.org/2003/linkbase" />
          <labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="cmcl_MotapaProjectMember" xlink:to="cmcl_MotapaProjectMember_lbl" xmlns="http://www.xbrl.org/2003/linkbase" />
          <label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:label="cmcl_MotapaProjectMember_lbl" xml:lang="en-US" xmlns="http://www.xbrl.org/2003/linkbase">This member stands for the project of Motapa.</label>
          <label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/label" xlink:label="cmcl_MotapaProjectMember_lbl" xml:lang="en-US" xmlns="http://www.xbrl.org/2003/linkbase">Motapa Project [Member]</label>
          <label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/terseLabel" xlink:label="cmcl_MotapaProjectMember_lbl" xml:lang="en-US" xmlns="http://www.xbrl.org/2003/linkbase">Motapa</label>
          <loc xlink:type="locator" xlink:href="#cmcl_CaledoniaMiningSouthAfricaProprietaryLimitedProjectMember" xlink:label="cmcl_CaledoniaMiningSouthAfricaProprietaryLimitedProjectMember" xmlns="http://www.xbrl.org/2003/linkbase" />
          <labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="cmcl_CaledoniaMiningSouthAfricaProprietaryLimitedProjectMember" xlink:to="cmcl_CaledoniaMiningSouthAfricaProprietaryLimitedProjectMember_lbl" xmlns="http://www.xbrl.org/2003/linkbase" />
          <label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:label="cmcl_CaledoniaMiningSouthAfricaProprietaryLimitedProjectMember_lbl" xml:lang="en-US" xmlns="http://www.xbrl.org/2003/linkbase">This member stands for the project of Caledonia Mining South Africa Proprietary Limited.</label>
          <label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/label" xlink:label="cmcl_CaledoniaMiningSouthAfricaProprietaryLimitedProjectMember_lbl" xml:lang="en-US" xmlns="http://www.xbrl.org/2003/linkbase">Caledonia Mining South Africa Proprietary Limited Project [Member]</label>
          <label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/terseLabel" xlink:label="cmcl_CaledoniaMiningSouthAfricaProprietaryLimitedProjectMember_lbl" xml:lang="en-US" xmlns="http://www.xbrl.org/2003/linkbase">Caledonia Mining South Africa Proprietary Limited</label>
          <loc xlink:type="locator" xlink:href="https://xbrl.sec.gov/country/2025/country-2025.xsd#country_ZW" xlink:label="country_ZW" xmlns="http://www.xbrl.org/2003/linkbase" />
          <labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="country_ZW" xlink:to="country_ZW_lbl" xmlns="http://www.xbrl.org/2003/linkbase" />
          <label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/label" xlink:label="country_ZW_lbl" xml:lang="en-US" xmlns="http://www.xbrl.org/2003/linkbase">ZIMBABWE</label>
          <loc xlink:type="locator" xlink:href="https://xbrl.sec.gov/country/2025/country-2025.xsd#country_ZA" xlink:label="country_ZA" xmlns="http://www.xbrl.org/2003/linkbase" />
          <labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="country_ZA" xlink:to="country_ZA_lbl" xmlns="http://www.xbrl.org/2003/linkbase" />
          <label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/label" xlink:label="country_ZA_lbl" xml:lang="en-US" xmlns="http://www.xbrl.org/2003/linkbase">SOUTH AFRICA</label>
          <loc xlink:type="locator" xlink:href="#cmcl_ZimbabweRevenueAuthorityMember" xlink:label="cmcl_ZimbabweRevenueAuthorityMember" xmlns="http://www.xbrl.org/2003/linkbase" />
          <labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="cmcl_ZimbabweRevenueAuthorityMember" xlink:to="cmcl_ZimbabweRevenueAuthorityMember_lbl" xmlns="http://www.xbrl.org/2003/linkbase" />
          <label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:label="cmcl_ZimbabweRevenueAuthorityMember_lbl" xml:lang="en-US" xmlns="http://www.xbrl.org/2003/linkbase">This member stands for the agency of the Zimbabwe Revenue Authority.</label>
          <label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/label" xlink:label="cmcl_ZimbabweRevenueAuthorityMember_lbl" xml:lang="en-US" xmlns="http://www.xbrl.org/2003/linkbase">Zimbabwe Revenue Authority [Member]</label>
          <label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/terseLabel" xlink:label="cmcl_ZimbabweRevenueAuthorityMember_lbl" xml:lang="en-US" xmlns="http://www.xbrl.org/2003/linkbase">Zimbabwe Revenue Authority</label>
          <loc xlink:type="locator" xlink:href="#cmcl_MinistryOfMinesMember" xlink:label="cmcl_MinistryOfMinesMember" xmlns="http://www.xbrl.org/2003/linkbase" />
          <labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="cmcl_MinistryOfMinesMember" xlink:to="cmcl_MinistryOfMinesMember_lbl" xmlns="http://www.xbrl.org/2003/linkbase" />
          <label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:label="cmcl_MinistryOfMinesMember_lbl" xml:lang="en-US" xmlns="http://www.xbrl.org/2003/linkbase">This member stands for the agency of the Ministry of Mines.</label>
          <label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/label" xlink:label="cmcl_MinistryOfMinesMember_lbl" xml:lang="en-US" xmlns="http://www.xbrl.org/2003/linkbase">Ministry of Mines [Member]</label>
          <label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/terseLabel" xlink:label="cmcl_MinistryOfMinesMember_lbl" xml:lang="en-US" xmlns="http://www.xbrl.org/2003/linkbase">Ministry of Mines</label>
          <loc xlink:type="locator" xlink:href="#cmcl_NationalIndigenisationAndEconomicEmpowermentFundMember" xlink:label="cmcl_NationalIndigenisationAndEconomicEmpowermentFundMember" xmlns="http://www.xbrl.org/2003/linkbase" />
          <labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="cmcl_NationalIndigenisationAndEconomicEmpowermentFundMember" xlink:to="cmcl_NationalIndigenisationAndEconomicEmpowermentFundMember_lbl" xmlns="http://www.xbrl.org/2003/linkbase" />
          <label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:label="cmcl_NationalIndigenisationAndEconomicEmpowermentFundMember_lbl" xml:lang="en-US" xmlns="http://www.xbrl.org/2003/linkbase">This member stands for the agency of the National Indigenisation and Economic Empowerment Fund.</label>
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          <label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/terseLabel" xlink:label="cmcl_NationalIndigenisationAndEconomicEmpowermentFundMember_lbl" xml:lang="en-US" xmlns="http://www.xbrl.org/2003/linkbase">National Indigenisation and Economic Empowerment Fund</label>
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          <label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:label="cmcl_SouthAfricanRevenueAuthorityMember_lbl" xml:lang="en-US" xmlns="http://www.xbrl.org/2003/linkbase">This member stands for the agency of the South African Revenue Authority.</label>
          <label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/label" xlink:label="cmcl_SouthAfricanRevenueAuthorityMember_lbl" xml:lang="en-US" xmlns="http://www.xbrl.org/2003/linkbase">South African Revenue Authority [Member]</label>
          <label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/terseLabel" xlink:label="cmcl_SouthAfricanRevenueAuthorityMember_lbl" xml:lang="en-US" xmlns="http://www.xbrl.org/2003/linkbase">South African Revenue Authority</label>
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        <presentationLink xlink:role="http://xbrl.sec.gov/rxp/role/ByCategory" xlink:type="extended" xlink:title="995600 - Disclosure - Payments, by Category" xmlns="http://www.xbrl.org/2003/linkbase" />
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          <loc xlink:type="locator" xlink:href="#cmcl_BlanketMineProjectMember" xlink:label="cmcl_BlanketMineProjectMember_639255931980998371" />
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          <loc xlink:type="locator" xlink:href="#cmcl_CaledoniaMiningSouthAfricaProprietaryLimitedProjectMember" xlink:label="cmcl_CaledoniaMiningSouthAfricaProprietaryLimitedProjectMember_639255931980998371" />
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        <presentationLink xlink:role="http://xbrl.sec.gov/rxp/role/ByGovernment" xlink:type="extended" xlink:title="995602 - Disclosure - Payments, by Government" xmlns="http://www.xbrl.org/2003/linkbase">
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</xsd:schema>
