<?xml version="1.0" encoding="utf-8"?>
<!--Generated by DFIN XBRL Instance Document - http://www.dfinsolutions.com/ - Version R3.0 - on 05-August-2026 [11:57:13] {PM}-->
<schema targetNamespace="http://www.nvqmif.com/20260531" elementFormDefault="qualified" xmlns:cik0000897421="http://www.nvqmif.com/20260531" xmlns="http://www.w3.org/2001/XMLSchema" xmlns:link="http://www.xbrl.org/2003/linkbase" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xbrli="http://www.xbrl.org/2003/instance" xmlns:xbrldt="http://xbrl.org/2005/xbrldt" xmlns:xl="http://www.xbrl.org/2003/XLink" xmlns:us-gaap="http://fasb.org/us-gaap/2026" xmlns:country="http://xbrl.sec.gov/country/2026" xmlns:currency="http://xbrl.sec.gov/currency/2026" xmlns:dei="http://xbrl.sec.gov/dei/2026" xmlns:exch="http://xbrl.sec.gov/exch/2026" xmlns:naics="http://xbrl.sec.gov/naics/2026" xmlns:sic="http://xbrl.sec.gov/sic/2026" xmlns:us-types="http://fasb.org/us-types/2026" xmlns:stpr="http://xbrl.sec.gov/stpr/2026" xmlns:deprecated="http://www.xbrl.org/2009/arcrole/fact-explanatoryFact" xmlns:srt="http://fasb.org/srt/2026" xmlns:srt-types="http://fasb.org/srt-types/2026" xmlns:dtr-types="http://www.xbrl.org/dtr/type/2024-01-31" xmlns:cef="http://xbrl.sec.gov/cef/2026" xmlns:cef-pre="http://xbrl.sec.gov/cef-pre/2026" xmlns:fnd="http://xbrl.sec.gov/fnd/2026">
  <annotation>
    <appinfo>
      <link:roleType roleURI="http://www.nvqmif.com/role/N2FeeTable" id="N2FeeTable">
        <link:definition>1001 - Disclosure - N-2 - [Fee Table]</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
      </link:roleType>
      <link:roleType roleURI="http://www.nvqmif.com/role/N2SeniorSecurities" id="N2SeniorSecurities">
        <link:definition>1002 - Disclosure - N-2 - [Senior Securities]</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
      </link:roleType>
      <link:roleType roleURI="http://www.nvqmif.com/role/N2InvestmentObjectives" id="N2InvestmentObjectives">
        <link:definition>1003 - Disclosure - N-2 - [Investment Objectives]</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
      </link:roleType>
      <link:roleType roleURI="http://www.nvqmif.com/role/N2RiskFactors" id="N2RiskFactors">
        <link:definition>1004 - Disclosure - N-2 - [Risk Factors]</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
      </link:roleType>
      <link:roleType roleURI="http://www.nvqmif.com/role/N2EffectsOfLeverage" id="N2EffectsOfLeverage">
        <link:definition>1005 - Disclosure - N-2 - [Effects of Leverage]</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
      </link:roleType>
      <link:roleType roleURI="http://www.nvqmif.com/role/N2SharePriceTable" id="N2SharePriceTable">
        <link:definition>1006 - Disclosure - N-2 - [Share Price Table]</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
      </link:roleType>
      <link:roleType roleURI="http://www.nvqmif.com/role/N2OutstandingSecurities" id="N2OutstandingSecurities">
        <link:definition>1007 - Disclosure - N-2 - [Outstanding Securities]</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
      </link:roleType>
      <link:linkbase id="lnk" >
        <link:roleRef xlink:type="simple" xlink:href="https://xbrl.sec.gov/cef/2026/cef-2026.xsd#N2" roleURI="http://xbrl.sec.gov/cef/role/N2"  />
        <link:roleRef xlink:type="simple" xlink:href="https://xbrl.sec.gov/cef/2026/cef-2026.xsd#SecurityOnly" roleURI="http://xbrl.sec.gov/cef/role/SecurityOnly"  />
        <link:roleRef xlink:type="simple" xlink:href="https://xbrl.sec.gov/cef/2026/cef-2026.xsd#RiskOnly" roleURI="http://xbrl.sec.gov/cef/role/RiskOnly"  />
        <link:presentationLink xlink:type="extended" xlink:role="http://xbrl.sec.gov/cef/role/N2" >
          <link:loc xlink:type="locator" xlink:href="https://xbrl.sec.gov/cef/2026/cef-2026.xsd#cef_AllRisksMember" xlink:label="loc_cef_AllRisksMember_200074" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_AlternativeMinimumTaxRiskMember" xlink:label="loc_cik0000897421_AlternativeMinimumTaxRiskMember_200633" />
          <link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_AlternativeMinimumTaxRiskMember_200633" use="optional" order="1" preferredLabel="http://www.xbrl.org/2003/role/label" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_BelowInvestmentGradeRiskMember" xlink:label="loc_cik0000897421_BelowInvestmentGradeRiskMember_200634" />
          <link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_BelowInvestmentGradeRiskMember_200634" use="optional" order="2" preferredLabel="http://www.xbrl.org/2003/role/label" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_CallRiskMember" xlink:label="loc_cik0000897421_CallRiskMember_200635" />
          <link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_CallRiskMember_200635" use="optional" order="3" preferredLabel="http://www.xbrl.org/2003/role/label" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_CreditRisksMember" xlink:label="loc_cik0000897421_CreditRisksMember_200636" />
          <link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_CreditRisksMember_200636" use="optional" order="4" preferredLabel="http://www.xbrl.org/2003/role/label" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_CreditSpreadRiskMember" xlink:label="loc_cik0000897421_CreditSpreadRiskMember_200681" />
          <link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_CreditSpreadRiskMember_200681" use="optional" order="5" preferredLabel="http://www.xbrl.org/2003/role/label" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_DefaultedOrDistressedSecuritiesRiskMember" xlink:label="loc_cik0000897421_DefaultedOrDistressedSecuritiesRiskMember_200637" />
          <link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_DefaultedOrDistressedSecuritiesRiskMember_200637" use="optional" order="6" preferredLabel="http://www.xbrl.org/2003/role/label" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_DeflationRiskMember" xlink:label="loc_cik0000897421_DeflationRiskMember_200638" />
          <link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_DeflationRiskMember_200638" use="optional" order="7" preferredLabel="http://www.xbrl.org/2003/role/label" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_DerivativesRiskMember" xlink:label="loc_cik0000897421_DerivativesRiskMember_200640" />
          <link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_DerivativesRiskMember_200640" use="optional" order="8" preferredLabel="http://www.xbrl.org/2003/role/label" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_DurationRiskMember" xlink:label="loc_cik0000897421_DurationRiskMember_200639" />
          <link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_DurationRiskMember_200639" use="optional" order="9" preferredLabel="http://www.xbrl.org/2003/role/label" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_EconomicSectorRiskMember" xlink:label="loc_cik0000897421_EconomicSectorRiskMember_200641" />
          <link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_EconomicSectorRiskMember_200641" use="optional" order="10" preferredLabel="http://www.xbrl.org/2003/role/label" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_FinancialFuturesAndOptionsTransactionsRiskMember" xlink:label="loc_cik0000897421_FinancialFuturesAndOptionsTransactionsRiskMember_200642" />
          <link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_FinancialFuturesAndOptionsTransactionsRiskMember_200642" use="optional" order="11" preferredLabel="http://www.xbrl.org/2003/role/label" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_FloatingAndVariableRateSecuritiesRiskMember" xlink:label="loc_cik0000897421_FloatingAndVariableRateSecuritiesRiskMember_200643" />
          <link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_FloatingAndVariableRateSecuritiesRiskMember_200643" use="optional" order="12" preferredLabel="http://www.xbrl.org/2003/role/label" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_HedgingRiskMember" xlink:label="loc_cik0000897421_HedgingRiskMember_200644" />
          <link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_HedgingRiskMember_200644" use="optional" order="13" preferredLabel="http://www.xbrl.org/2003/role/label" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_IncomeRiskMember" xlink:label="loc_cik0000897421_IncomeRiskMember_200645" />
          <link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_IncomeRiskMember_200645" use="optional" order="14" preferredLabel="http://www.xbrl.org/2003/role/label" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_InflationRiskMember" xlink:label="loc_cik0000897421_InflationRiskMember_200648" />
          <link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_InflationRiskMember_200648" use="optional" order="15" preferredLabel="http://www.xbrl.org/2003/role/label" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_InsuranceRiskMember" xlink:label="loc_cik0000897421_InsuranceRiskMember_200646" />
          <link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_InsuranceRiskMember_200646" use="optional" order="16" preferredLabel="http://www.xbrl.org/2003/role/label" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_InverseFloatingRateSecuritiesRiskMember" xlink:label="loc_cik0000897421_InverseFloatingRateSecuritiesRiskMember_200649" />
          <link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_InverseFloatingRateSecuritiesRiskMember_200649" use="optional" order="17" preferredLabel="http://www.xbrl.org/2003/role/label" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_MunicipalSecuritiesRiskMember" xlink:label="loc_cik0000897421_MunicipalSecuritiesRiskMember_200650" />
          <link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_MunicipalSecuritiesRiskMember_200650" use="optional" order="18" preferredLabel="http://www.xbrl.org/2003/role/label" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_MunicipalSecuritiesMarketLiquidityRiskMember" xlink:label="loc_cik0000897421_MunicipalSecuritiesMarketLiquidityRiskMember_200651" />
          <link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_MunicipalSecuritiesMarketLiquidityRiskMember_200651" use="optional" order="19" preferredLabel="http://www.xbrl.org/2003/role/label" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_MunicipalSecuritiesMarketRiskMember" xlink:label="loc_cik0000897421_MunicipalSecuritiesMarketRiskMember_200652" />
          <link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_MunicipalSecuritiesMarketRiskMember_200652" use="optional" order="20" preferredLabel="http://www.xbrl.org/2003/role/label" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_OtherInvestmentCompaniesRiskMember" xlink:label="loc_cik0000897421_OtherInvestmentCompaniesRiskMember_200653" />
          <link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_OtherInvestmentCompaniesRiskMember_200653" use="optional" order="21" preferredLabel="http://www.xbrl.org/2003/role/label" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_PuertoRicoMunicipalSecuritiesMarketRiskMember" xlink:label="loc_cik0000897421_PuertoRicoMunicipalSecuritiesMarketRiskMember_200654" />
          <link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_PuertoRicoMunicipalSecuritiesMarketRiskMember_200654" use="optional" order="22" preferredLabel="http://www.xbrl.org/2003/role/label" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_ReinvestmentRiskMember" xlink:label="loc_cik0000897421_ReinvestmentRiskMember_200655" />
          <link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_ReinvestmentRiskMember_200655" use="optional" order="23" preferredLabel="http://www.xbrl.org/2003/role/label" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_RestrictedAndIlliquidInvestmentsRiskMember" xlink:label="loc_cik0000897421_RestrictedAndIlliquidInvestmentsRiskMember_200656" />
          <link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_RestrictedAndIlliquidInvestmentsRiskMember_200656" use="optional" order="24" preferredLabel="http://www.xbrl.org/2003/role/label" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_SpecialConsiderationsRelatedToSingleStateConcentrationRiskMember" xlink:label="loc_cik0000897421_SpecialConsiderationsRelatedToSingleStateConcentrationRiskMember_200657" />
          <link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_SpecialConsiderationsRelatedToSingleStateConcentrationRiskMember_200657" use="optional" order="25" preferredLabel="http://www.xbrl.org/2003/role/label" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_SpecialRisksRelatedToCertainMunicipalObligationsMember" xlink:label="loc_cik0000897421_SpecialRisksRelatedToCertainMunicipalObligationsMember_200658" />
          <link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_SpecialRisksRelatedToCertainMunicipalObligationsMember_200658" use="optional" order="26" preferredLabel="http://www.xbrl.org/2003/role/label" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_StructuredProductsRiskMember" xlink:label="loc_cik0000897421_StructuredProductsRiskMember_200659" />
          <link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_StructuredProductsRiskMember_200659" use="optional" order="27" preferredLabel="http://www.xbrl.org/2003/role/label" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_SwapTransactionsRiskMember" xlink:label="loc_cik0000897421_SwapTransactionsRiskMember_200661" />
          <link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_SwapTransactionsRiskMember_200661" use="optional" order="28" preferredLabel="http://www.xbrl.org/2003/role/label" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_TaxRiskMember" xlink:label="loc_cik0000897421_TaxRiskMember_200660" />
          <link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_TaxRiskMember_200660" use="optional" order="29" preferredLabel="http://www.xbrl.org/2003/role/label" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_TaxabilityRiskMember" xlink:label="loc_cik0000897421_TaxabilityRiskMember_200662" />
          <link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_TaxabilityRiskMember_200662" use="optional" order="30" preferredLabel="http://www.xbrl.org/2003/role/label" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_TobaccoSettlementBondRiskMember" xlink:label="loc_cik0000897421_TobaccoSettlementBondRiskMember_200663" />
          <link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_TobaccoSettlementBondRiskMember_200663" use="optional" order="31" preferredLabel="http://www.xbrl.org/2003/role/label" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_UnratedSecuritiesRiskMember" xlink:label="loc_cik0000897421_UnratedSecuritiesRiskMember_200664" />
          <link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_UnratedSecuritiesRiskMember_200664" use="optional" order="32" preferredLabel="http://www.xbrl.org/2003/role/label" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_ValuationRiskMember" xlink:label="loc_cik0000897421_ValuationRiskMember_200665" />
          <link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_ValuationRiskMember_200665" use="optional" order="33" preferredLabel="http://www.xbrl.org/2003/role/label" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_WhenissuedAndDelayeddeliveryTransactionsRiskMember" xlink:label="loc_cik0000897421_WhenissuedAndDelayeddeliveryTransactionsRiskMember_200666" />
          <link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_WhenissuedAndDelayeddeliveryTransactionsRiskMember_200666" use="optional" order="34" preferredLabel="http://www.xbrl.org/2003/role/label" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_ZeroCouponBondsRiskMember" xlink:label="loc_cik0000897421_ZeroCouponBondsRiskMember_200667" />
          <link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_ZeroCouponBondsRiskMember_200667" use="optional" order="35" preferredLabel="http://www.xbrl.org/2003/role/label" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_AntitakeoverProvisionsMember" xlink:label="loc_cik0000897421_AntitakeoverProvisionsMember_200668" />
          <link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_AntitakeoverProvisionsMember_200668" use="optional" order="36" preferredLabel="http://www.xbrl.org/2003/role/label" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_CounterpartyRiskMember" xlink:label="loc_cik0000897421_CounterpartyRiskMember_200669" />
          <link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_CounterpartyRiskMember_200669" use="optional" order="37" preferredLabel="http://www.xbrl.org/2003/role/label" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_CybersecurityRiskMember" xlink:label="loc_cik0000897421_CybersecurityRiskMember_200670" />
          <link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_CybersecurityRiskMember_200670" use="optional" order="38" preferredLabel="http://www.xbrl.org/2003/role/label" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_EconomicAndPoliticalEventsRiskMember" xlink:label="loc_cik0000897421_EconomicAndPoliticalEventsRiskMember_200671" />
          <link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_EconomicAndPoliticalEventsRiskMember_200671" use="optional" order="39" preferredLabel="http://www.xbrl.org/2003/role/label" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_FundTaxRiskMember" xlink:label="loc_cik0000897421_FundTaxRiskMember_200672" />
          <link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_FundTaxRiskMember_200672" use="optional" order="40" preferredLabel="http://www.xbrl.org/2003/role/label" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_GlobalEconomicRiskMember" xlink:label="loc_cik0000897421_GlobalEconomicRiskMember_200673" />
          <link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_GlobalEconomicRiskMember_200673" use="optional" order="41" preferredLabel="http://www.xbrl.org/2003/role/label" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_InvestmentAndMarketRiskMember" xlink:label="loc_cik0000897421_InvestmentAndMarketRiskMember_200675" />
          <link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_InvestmentAndMarketRiskMember_200675" use="optional" order="42" preferredLabel="http://www.xbrl.org/2003/role/label" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_LegislationAndRegulatoryRiskMember" xlink:label="loc_cik0000897421_LegislationAndRegulatoryRiskMember_200676" />
          <link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_LegislationAndRegulatoryRiskMember_200676" use="optional" order="43" preferredLabel="http://www.xbrl.org/2003/role/label" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_LeverageRiskMember" xlink:label="loc_cik0000897421_LeverageRiskMember_200677" />
          <link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_LeverageRiskMember_200677" use="optional" order="44" preferredLabel="http://www.xbrl.org/2003/role/label" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_MarketDiscountFromNetAssetValueMember" xlink:label="loc_cik0000897421_MarketDiscountFromNetAssetValueMember_200678" />
          <link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_MarketDiscountFromNetAssetValueMember_200678" use="optional" order="45" preferredLabel="http://www.xbrl.org/2003/role/label" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_RecentMarketConditionsMember" xlink:label="loc_cik0000897421_RecentMarketConditionsMember_200679" />
          <link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_RecentMarketConditionsMember_200679" use="optional" order="46" preferredLabel="http://www.xbrl.org/2003/role/label" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_ReverseRepurchaseAgreementRiskMember" xlink:label="loc_cik0000897421_ReverseRepurchaseAgreementRiskMember_200680" />
          <link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_ReverseRepurchaseAgreementRiskMember_200680" use="optional" order="47" preferredLabel="http://www.xbrl.org/2003/role/label" />
          <link:loc xlink:type="locator" xlink:href="https://xbrl.fasb.org/us-gaap/2026/elts/us-gaap-2026.xsd#us-gaap_ClassOfStockDomain" xlink:label="loc_us-gaap_ClassOfStockDomain_200072" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_CommonSharesMember" xlink:label="loc_cik0000897421_CommonSharesMember_200631" />
          <link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_us-gaap_ClassOfStockDomain_200072" xlink:to="loc_cik0000897421_CommonSharesMember_200631" use="optional" order="48" preferredLabel="http://www.xbrl.org/2003/role/label" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_VariableRateDemandPreferredSharesMember" xlink:label="loc_cik0000897421_VariableRateDemandPreferredSharesMember_200632" />
          <link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_us-gaap_ClassOfStockDomain_200072" xlink:to="loc_cik0000897421_VariableRateDemandPreferredSharesMember_200632" use="optional" order="49" preferredLabel="http://www.xbrl.org/2003/role/label" />
          <link:loc xlink:type="locator" xlink:href="https://xbrl.sec.gov/dei/2026/dei-2026.xsd#dei_AddressTypeDomain" xlink:label="loc_dei_AddressTypeDomain_200069" />
        </link:presentationLink>
        <link:arcroleRef arcroleURI="http://xbrl.org/int/dim/arcrole/domain-member" xlink:type="simple" xlink:href="http://www.xbrl.org/2005/xbrldt-2005.xsd#domain-member"  />
        <link:definitionLink xlink:type="extended" xlink:role="http://xbrl.sec.gov/cef/role/SecurityOnly" >
          <link:loc xlink:type="locator" xlink:href="https://xbrl.fasb.org/us-gaap/2026/elts/us-gaap-2026.xsd#us-gaap_ClassOfStockDomain" xlink:label="loc_us-gaap_ClassOfStockDomain_200072" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_CommonSharesMember" xlink:label="loc_cik0000897421_CommonSharesMember_200631" />
          <link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_us-gaap_ClassOfStockDomain_200072" xlink:to="loc_cik0000897421_CommonSharesMember_200631" use="optional" order="1" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_VariableRateDemandPreferredSharesMember" xlink:label="loc_cik0000897421_VariableRateDemandPreferredSharesMember_200632" />
          <link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_us-gaap_ClassOfStockDomain_200072" xlink:to="loc_cik0000897421_VariableRateDemandPreferredSharesMember_200632" use="optional" order="2" />
        </link:definitionLink>
        <link:definitionLink xlink:type="extended" xlink:role="http://xbrl.sec.gov/cef/role/RiskOnly" >
          <link:loc xlink:type="locator" xlink:href="https://xbrl.sec.gov/cef/2026/cef-2026.xsd#cef_AllRisksMember" xlink:label="loc_cef_AllRisksMember_200074" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_AlternativeMinimumTaxRiskMember" xlink:label="loc_cik0000897421_AlternativeMinimumTaxRiskMember_200633" />
          <link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_AlternativeMinimumTaxRiskMember_200633" use="optional" order="3" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_BelowInvestmentGradeRiskMember" xlink:label="loc_cik0000897421_BelowInvestmentGradeRiskMember_200634" />
          <link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_BelowInvestmentGradeRiskMember_200634" use="optional" order="4" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_CallRiskMember" xlink:label="loc_cik0000897421_CallRiskMember_200635" />
          <link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_CallRiskMember_200635" use="optional" order="5" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_CreditRisksMember" xlink:label="loc_cik0000897421_CreditRisksMember_200636" />
          <link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_CreditRisksMember_200636" use="optional" order="6" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_DefaultedOrDistressedSecuritiesRiskMember" xlink:label="loc_cik0000897421_DefaultedOrDistressedSecuritiesRiskMember_200637" />
          <link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_DefaultedOrDistressedSecuritiesRiskMember_200637" use="optional" order="7" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_DeflationRiskMember" xlink:label="loc_cik0000897421_DeflationRiskMember_200638" />
          <link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_DeflationRiskMember_200638" use="optional" order="8" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_DurationRiskMember" xlink:label="loc_cik0000897421_DurationRiskMember_200639" />
          <link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_DurationRiskMember_200639" use="optional" order="9" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_DerivativesRiskMember" xlink:label="loc_cik0000897421_DerivativesRiskMember_200640" />
          <link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_DerivativesRiskMember_200640" use="optional" order="10" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_EconomicSectorRiskMember" xlink:label="loc_cik0000897421_EconomicSectorRiskMember_200641" />
          <link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_EconomicSectorRiskMember_200641" use="optional" order="11" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_FinancialFuturesAndOptionsTransactionsRiskMember" xlink:label="loc_cik0000897421_FinancialFuturesAndOptionsTransactionsRiskMember_200642" />
          <link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_FinancialFuturesAndOptionsTransactionsRiskMember_200642" use="optional" order="12" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_FloatingAndVariableRateSecuritiesRiskMember" xlink:label="loc_cik0000897421_FloatingAndVariableRateSecuritiesRiskMember_200643" />
          <link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_FloatingAndVariableRateSecuritiesRiskMember_200643" use="optional" order="13" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_HedgingRiskMember" xlink:label="loc_cik0000897421_HedgingRiskMember_200644" />
          <link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_HedgingRiskMember_200644" use="optional" order="14" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_IncomeRiskMember" xlink:label="loc_cik0000897421_IncomeRiskMember_200645" />
          <link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_IncomeRiskMember_200645" use="optional" order="15" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_InsuranceRiskMember" xlink:label="loc_cik0000897421_InsuranceRiskMember_200646" />
          <link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_InsuranceRiskMember_200646" use="optional" order="16" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_InflationRiskMember" xlink:label="loc_cik0000897421_InflationRiskMember_200648" />
          <link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_InflationRiskMember_200648" use="optional" order="17" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_InverseFloatingRateSecuritiesRiskMember" xlink:label="loc_cik0000897421_InverseFloatingRateSecuritiesRiskMember_200649" />
          <link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_InverseFloatingRateSecuritiesRiskMember_200649" use="optional" order="18" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_MunicipalSecuritiesRiskMember" xlink:label="loc_cik0000897421_MunicipalSecuritiesRiskMember_200650" />
          <link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_MunicipalSecuritiesRiskMember_200650" use="optional" order="19" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_MunicipalSecuritiesMarketLiquidityRiskMember" xlink:label="loc_cik0000897421_MunicipalSecuritiesMarketLiquidityRiskMember_200651" />
          <link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_MunicipalSecuritiesMarketLiquidityRiskMember_200651" use="optional" order="20" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_MunicipalSecuritiesMarketRiskMember" xlink:label="loc_cik0000897421_MunicipalSecuritiesMarketRiskMember_200652" />
          <link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_MunicipalSecuritiesMarketRiskMember_200652" use="optional" order="21" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_OtherInvestmentCompaniesRiskMember" xlink:label="loc_cik0000897421_OtherInvestmentCompaniesRiskMember_200653" />
          <link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_OtherInvestmentCompaniesRiskMember_200653" use="optional" order="22" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_PuertoRicoMunicipalSecuritiesMarketRiskMember" xlink:label="loc_cik0000897421_PuertoRicoMunicipalSecuritiesMarketRiskMember_200654" />
          <link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_PuertoRicoMunicipalSecuritiesMarketRiskMember_200654" use="optional" order="23" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_ReinvestmentRiskMember" xlink:label="loc_cik0000897421_ReinvestmentRiskMember_200655" />
          <link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_ReinvestmentRiskMember_200655" use="optional" order="24" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_RestrictedAndIlliquidInvestmentsRiskMember" xlink:label="loc_cik0000897421_RestrictedAndIlliquidInvestmentsRiskMember_200656" />
          <link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_RestrictedAndIlliquidInvestmentsRiskMember_200656" use="optional" order="25" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_SpecialConsiderationsRelatedToSingleStateConcentrationRiskMember" xlink:label="loc_cik0000897421_SpecialConsiderationsRelatedToSingleStateConcentrationRiskMember_200657" />
          <link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_SpecialConsiderationsRelatedToSingleStateConcentrationRiskMember_200657" use="optional" order="26" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_SpecialRisksRelatedToCertainMunicipalObligationsMember" xlink:label="loc_cik0000897421_SpecialRisksRelatedToCertainMunicipalObligationsMember_200658" />
          <link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_SpecialRisksRelatedToCertainMunicipalObligationsMember_200658" use="optional" order="27" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_StructuredProductsRiskMember" xlink:label="loc_cik0000897421_StructuredProductsRiskMember_200659" />
          <link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_StructuredProductsRiskMember_200659" use="optional" order="28" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_TaxRiskMember" xlink:label="loc_cik0000897421_TaxRiskMember_200660" />
          <link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_TaxRiskMember_200660" use="optional" order="29" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_SwapTransactionsRiskMember" xlink:label="loc_cik0000897421_SwapTransactionsRiskMember_200661" />
          <link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_SwapTransactionsRiskMember_200661" use="optional" order="30" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_TaxabilityRiskMember" xlink:label="loc_cik0000897421_TaxabilityRiskMember_200662" />
          <link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_TaxabilityRiskMember_200662" use="optional" order="31" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_TobaccoSettlementBondRiskMember" xlink:label="loc_cik0000897421_TobaccoSettlementBondRiskMember_200663" />
          <link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_TobaccoSettlementBondRiskMember_200663" use="optional" order="32" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_UnratedSecuritiesRiskMember" xlink:label="loc_cik0000897421_UnratedSecuritiesRiskMember_200664" />
          <link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_UnratedSecuritiesRiskMember_200664" use="optional" order="33" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_ValuationRiskMember" xlink:label="loc_cik0000897421_ValuationRiskMember_200665" />
          <link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_ValuationRiskMember_200665" use="optional" order="34" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_WhenissuedAndDelayeddeliveryTransactionsRiskMember" xlink:label="loc_cik0000897421_WhenissuedAndDelayeddeliveryTransactionsRiskMember_200666" />
          <link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_WhenissuedAndDelayeddeliveryTransactionsRiskMember_200666" use="optional" order="35" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_ZeroCouponBondsRiskMember" xlink:label="loc_cik0000897421_ZeroCouponBondsRiskMember_200667" />
          <link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_ZeroCouponBondsRiskMember_200667" use="optional" order="36" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_AntitakeoverProvisionsMember" xlink:label="loc_cik0000897421_AntitakeoverProvisionsMember_200668" />
          <link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_AntitakeoverProvisionsMember_200668" use="optional" order="37" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_CounterpartyRiskMember" xlink:label="loc_cik0000897421_CounterpartyRiskMember_200669" />
          <link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_CounterpartyRiskMember_200669" use="optional" order="38" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_CybersecurityRiskMember" xlink:label="loc_cik0000897421_CybersecurityRiskMember_200670" />
          <link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_CybersecurityRiskMember_200670" use="optional" order="39" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_EconomicAndPoliticalEventsRiskMember" xlink:label="loc_cik0000897421_EconomicAndPoliticalEventsRiskMember_200671" />
          <link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_EconomicAndPoliticalEventsRiskMember_200671" use="optional" order="40" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_FundTaxRiskMember" xlink:label="loc_cik0000897421_FundTaxRiskMember_200672" />
          <link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_FundTaxRiskMember_200672" use="optional" order="41" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_GlobalEconomicRiskMember" xlink:label="loc_cik0000897421_GlobalEconomicRiskMember_200673" />
          <link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_GlobalEconomicRiskMember_200673" use="optional" order="42" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_InvestmentAndMarketRiskMember" xlink:label="loc_cik0000897421_InvestmentAndMarketRiskMember_200675" />
          <link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_InvestmentAndMarketRiskMember_200675" use="optional" order="43" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_LegislationAndRegulatoryRiskMember" xlink:label="loc_cik0000897421_LegislationAndRegulatoryRiskMember_200676" />
          <link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_LegislationAndRegulatoryRiskMember_200676" use="optional" order="44" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_LeverageRiskMember" xlink:label="loc_cik0000897421_LeverageRiskMember_200677" />
          <link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_LeverageRiskMember_200677" use="optional" order="45" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_MarketDiscountFromNetAssetValueMember" xlink:label="loc_cik0000897421_MarketDiscountFromNetAssetValueMember_200678" />
          <link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_MarketDiscountFromNetAssetValueMember_200678" use="optional" order="46" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_RecentMarketConditionsMember" xlink:label="loc_cik0000897421_RecentMarketConditionsMember_200679" />
          <link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_RecentMarketConditionsMember_200679" use="optional" order="47" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_ReverseRepurchaseAgreementRiskMember" xlink:label="loc_cik0000897421_ReverseRepurchaseAgreementRiskMember_200680" />
          <link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_ReverseRepurchaseAgreementRiskMember_200680" use="optional" order="48" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_CreditSpreadRiskMember" xlink:label="loc_cik0000897421_CreditSpreadRiskMember_200681" />
          <link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_cef_AllRisksMember_200074" xlink:to="loc_cik0000897421_CreditSpreadRiskMember_200681" use="optional" order="49" />
        </link:definitionLink>
        <link:labelLink xlink:type="extended" xlink:role="http://www.xbrl.org/2003/role/link" >
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_CommonSharesMember" xlink:label="loc_cik0000897421_CommonSharesMember" />
          <link:label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/label" xlink:label="lab_cik0000897421_CommonSharesMember" xml:lang="en-US">Common Shares [Member]</link:label>
          <link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_cik0000897421_CommonSharesMember" xlink:to="lab_cik0000897421_CommonSharesMember" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_VariableRateDemandPreferredSharesMember" xlink:label="loc_cik0000897421_VariableRateDemandPreferredSharesMember" />
          <link:label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/label" xlink:label="lab_cik0000897421_VariableRateDemandPreferredSharesMember" xml:lang="en-US">Variable Rate Demand Preferred Shares [Member]</link:label>
          <link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_cik0000897421_VariableRateDemandPreferredSharesMember" xlink:to="lab_cik0000897421_VariableRateDemandPreferredSharesMember" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_AlternativeMinimumTaxRiskMember" xlink:label="loc_cik0000897421_AlternativeMinimumTaxRiskMember" />
          <link:label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/label" xlink:label="lab_cik0000897421_AlternativeMinimumTaxRiskMember" xml:lang="en-US">Alternative Minimum Tax Risk [Member]</link:label>
          <link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_cik0000897421_AlternativeMinimumTaxRiskMember" xlink:to="lab_cik0000897421_AlternativeMinimumTaxRiskMember" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_BelowInvestmentGradeRiskMember" xlink:label="loc_cik0000897421_BelowInvestmentGradeRiskMember" />
          <link:label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/label" xlink:label="lab_cik0000897421_BelowInvestmentGradeRiskMember" xml:lang="en-US">Below Investment Grade Risk [Member]</link:label>
          <link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_cik0000897421_BelowInvestmentGradeRiskMember" xlink:to="lab_cik0000897421_BelowInvestmentGradeRiskMember" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_CallRiskMember" xlink:label="loc_cik0000897421_CallRiskMember" />
          <link:label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/label" xlink:label="lab_cik0000897421_CallRiskMember" xml:lang="en-US">Call Risk [Member]</link:label>
          <link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_cik0000897421_CallRiskMember" xlink:to="lab_cik0000897421_CallRiskMember" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_CreditRisksMember" xlink:label="loc_cik0000897421_CreditRisksMember" />
          <link:label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/label" xlink:label="lab_cik0000897421_CreditRisksMember" xml:lang="en-US">Credit Risk [Member]</link:label>
          <link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_cik0000897421_CreditRisksMember" xlink:to="lab_cik0000897421_CreditRisksMember" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_DefaultedOrDistressedSecuritiesRiskMember" xlink:label="loc_cik0000897421_DefaultedOrDistressedSecuritiesRiskMember" />
          <link:label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/label" xlink:label="lab_cik0000897421_DefaultedOrDistressedSecuritiesRiskMember" xml:lang="en-US">Defaulted or Distressed Securities Risk [Member]</link:label>
          <link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_cik0000897421_DefaultedOrDistressedSecuritiesRiskMember" xlink:to="lab_cik0000897421_DefaultedOrDistressedSecuritiesRiskMember" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_DeflationRiskMember" xlink:label="loc_cik0000897421_DeflationRiskMember" />
          <link:label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/label" xlink:label="lab_cik0000897421_DeflationRiskMember" xml:lang="en-US">Deflation Risk [Member]</link:label>
          <link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_cik0000897421_DeflationRiskMember" xlink:to="lab_cik0000897421_DeflationRiskMember" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_DurationRiskMember" xlink:label="loc_cik0000897421_DurationRiskMember" />
          <link:label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/label" xlink:label="lab_cik0000897421_DurationRiskMember" xml:lang="en-US">Duration Risk [Member]</link:label>
          <link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_cik0000897421_DurationRiskMember" xlink:to="lab_cik0000897421_DurationRiskMember" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_DerivativesRiskMember" xlink:label="loc_cik0000897421_DerivativesRiskMember" />
          <link:label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/label" xlink:label="lab_cik0000897421_DerivativesRiskMember" xml:lang="en-US">Derivatives Risk [Member]</link:label>
          <link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_cik0000897421_DerivativesRiskMember" xlink:to="lab_cik0000897421_DerivativesRiskMember" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_EconomicSectorRiskMember" xlink:label="loc_cik0000897421_EconomicSectorRiskMember" />
          <link:label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/label" xlink:label="lab_cik0000897421_EconomicSectorRiskMember" xml:lang="en-US">Economic Sector Risk [Member]</link:label>
          <link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_cik0000897421_EconomicSectorRiskMember" xlink:to="lab_cik0000897421_EconomicSectorRiskMember" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_FinancialFuturesAndOptionsTransactionsRiskMember" xlink:label="loc_cik0000897421_FinancialFuturesAndOptionsTransactionsRiskMember" />
          <link:label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/label" xlink:label="lab_cik0000897421_FinancialFuturesAndOptionsTransactionsRiskMember" xml:lang="en-US">Financial Futures and Options Transactions Risk [Member]</link:label>
          <link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_cik0000897421_FinancialFuturesAndOptionsTransactionsRiskMember" xlink:to="lab_cik0000897421_FinancialFuturesAndOptionsTransactionsRiskMember" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_FloatingAndVariableRateSecuritiesRiskMember" xlink:label="loc_cik0000897421_FloatingAndVariableRateSecuritiesRiskMember" />
          <link:label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/label" xlink:label="lab_cik0000897421_FloatingAndVariableRateSecuritiesRiskMember" xml:lang="en-US">Floating and Variable Rate Securities Risk [Member]</link:label>
          <link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_cik0000897421_FloatingAndVariableRateSecuritiesRiskMember" xlink:to="lab_cik0000897421_FloatingAndVariableRateSecuritiesRiskMember" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_HedgingRiskMember" xlink:label="loc_cik0000897421_HedgingRiskMember" />
          <link:label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/label" xlink:label="lab_cik0000897421_HedgingRiskMember" xml:lang="en-US">Hedging Risk [Member]</link:label>
          <link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_cik0000897421_HedgingRiskMember" xlink:to="lab_cik0000897421_HedgingRiskMember" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_IncomeRiskMember" xlink:label="loc_cik0000897421_IncomeRiskMember" />
          <link:label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/label" xlink:label="lab_cik0000897421_IncomeRiskMember" xml:lang="en-US">Income Risk [Member]</link:label>
          <link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_cik0000897421_IncomeRiskMember" xlink:to="lab_cik0000897421_IncomeRiskMember" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_InsuranceRiskMember" xlink:label="loc_cik0000897421_InsuranceRiskMember" />
          <link:label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/label" xlink:label="lab_cik0000897421_InsuranceRiskMember" xml:lang="en-US">Insurance Risk [Member]</link:label>
          <link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_cik0000897421_InsuranceRiskMember" xlink:to="lab_cik0000897421_InsuranceRiskMember" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_InflationRiskMember" xlink:label="loc_cik0000897421_InflationRiskMember" />
          <link:label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/label" xlink:label="lab_cik0000897421_InflationRiskMember" xml:lang="en-US">Inflation Risk [Member]</link:label>
          <link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_cik0000897421_InflationRiskMember" xlink:to="lab_cik0000897421_InflationRiskMember" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_InverseFloatingRateSecuritiesRiskMember" xlink:label="loc_cik0000897421_InverseFloatingRateSecuritiesRiskMember" />
          <link:label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/label" xlink:label="lab_cik0000897421_InverseFloatingRateSecuritiesRiskMember" xml:lang="en-US">Inverse Floating Rate Securities Risk [Member]</link:label>
          <link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_cik0000897421_InverseFloatingRateSecuritiesRiskMember" xlink:to="lab_cik0000897421_InverseFloatingRateSecuritiesRiskMember" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_MunicipalSecuritiesRiskMember" xlink:label="loc_cik0000897421_MunicipalSecuritiesRiskMember" />
          <link:label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/label" xlink:label="lab_cik0000897421_MunicipalSecuritiesRiskMember" xml:lang="en-US">Municipal Securities Risk [Member]</link:label>
          <link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_cik0000897421_MunicipalSecuritiesRiskMember" xlink:to="lab_cik0000897421_MunicipalSecuritiesRiskMember" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_MunicipalSecuritiesMarketLiquidityRiskMember" xlink:label="loc_cik0000897421_MunicipalSecuritiesMarketLiquidityRiskMember" />
          <link:label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/label" xlink:label="lab_cik0000897421_MunicipalSecuritiesMarketLiquidityRiskMember" xml:lang="en-US">Municipal Securities Market Liquidity Risk [Member]</link:label>
          <link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_cik0000897421_MunicipalSecuritiesMarketLiquidityRiskMember" xlink:to="lab_cik0000897421_MunicipalSecuritiesMarketLiquidityRiskMember" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_MunicipalSecuritiesMarketRiskMember" xlink:label="loc_cik0000897421_MunicipalSecuritiesMarketRiskMember" />
          <link:label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/label" xlink:label="lab_cik0000897421_MunicipalSecuritiesMarketRiskMember" xml:lang="en-US">Municipal Securities Market Risk [Member]</link:label>
          <link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_cik0000897421_MunicipalSecuritiesMarketRiskMember" xlink:to="lab_cik0000897421_MunicipalSecuritiesMarketRiskMember" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_OtherInvestmentCompaniesRiskMember" xlink:label="loc_cik0000897421_OtherInvestmentCompaniesRiskMember" />
          <link:label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/label" xlink:label="lab_cik0000897421_OtherInvestmentCompaniesRiskMember" xml:lang="en-US">Other Investment Companies Risk [Member]</link:label>
          <link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_cik0000897421_OtherInvestmentCompaniesRiskMember" xlink:to="lab_cik0000897421_OtherInvestmentCompaniesRiskMember" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_PuertoRicoMunicipalSecuritiesMarketRiskMember" xlink:label="loc_cik0000897421_PuertoRicoMunicipalSecuritiesMarketRiskMember" />
          <link:label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/label" xlink:label="lab_cik0000897421_PuertoRicoMunicipalSecuritiesMarketRiskMember" xml:lang="en-US">Puerto Rico Municipal Securities Market Risk [Member]</link:label>
          <link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_cik0000897421_PuertoRicoMunicipalSecuritiesMarketRiskMember" xlink:to="lab_cik0000897421_PuertoRicoMunicipalSecuritiesMarketRiskMember" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_ReinvestmentRiskMember" xlink:label="loc_cik0000897421_ReinvestmentRiskMember" />
          <link:label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/label" xlink:label="lab_cik0000897421_ReinvestmentRiskMember" xml:lang="en-US">Reinvestment Risk [Member]</link:label>
          <link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_cik0000897421_ReinvestmentRiskMember" xlink:to="lab_cik0000897421_ReinvestmentRiskMember" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_RestrictedAndIlliquidInvestmentsRiskMember" xlink:label="loc_cik0000897421_RestrictedAndIlliquidInvestmentsRiskMember" />
          <link:label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/label" xlink:label="lab_cik0000897421_RestrictedAndIlliquidInvestmentsRiskMember" xml:lang="en-US">Restricted and Illiquid Investments Risk [Member]</link:label>
          <link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_cik0000897421_RestrictedAndIlliquidInvestmentsRiskMember" xlink:to="lab_cik0000897421_RestrictedAndIlliquidInvestmentsRiskMember" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_SpecialConsiderationsRelatedToSingleStateConcentrationRiskMember" xlink:label="loc_cik0000897421_SpecialConsiderationsRelatedToSingleStateConcentrationRiskMember" />
          <link:label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/label" xlink:label="lab_cik0000897421_SpecialConsiderationsRelatedToSingleStateConcentrationRiskMember" xml:lang="en-US">Special Considerations Related to Single State Concentration Risk [Member]</link:label>
          <link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_cik0000897421_SpecialConsiderationsRelatedToSingleStateConcentrationRiskMember" xlink:to="lab_cik0000897421_SpecialConsiderationsRelatedToSingleStateConcentrationRiskMember" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_SpecialRisksRelatedToCertainMunicipalObligationsMember" xlink:label="loc_cik0000897421_SpecialRisksRelatedToCertainMunicipalObligationsMember" />
          <link:label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/label" xlink:label="lab_cik0000897421_SpecialRisksRelatedToCertainMunicipalObligationsMember" xml:lang="en-US">Special Risks Related to Certain Municipal Obligations [Member]</link:label>
          <link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_cik0000897421_SpecialRisksRelatedToCertainMunicipalObligationsMember" xlink:to="lab_cik0000897421_SpecialRisksRelatedToCertainMunicipalObligationsMember" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_StructuredProductsRiskMember" xlink:label="loc_cik0000897421_StructuredProductsRiskMember" />
          <link:label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/label" xlink:label="lab_cik0000897421_StructuredProductsRiskMember" xml:lang="en-US">Structured Products Risk [Member]</link:label>
          <link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_cik0000897421_StructuredProductsRiskMember" xlink:to="lab_cik0000897421_StructuredProductsRiskMember" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_TaxRiskMember" xlink:label="loc_cik0000897421_TaxRiskMember" />
          <link:label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/label" xlink:label="lab_cik0000897421_TaxRiskMember" xml:lang="en-US">Tax Risk [Member]</link:label>
          <link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_cik0000897421_TaxRiskMember" xlink:to="lab_cik0000897421_TaxRiskMember" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_SwapTransactionsRiskMember" xlink:label="loc_cik0000897421_SwapTransactionsRiskMember" />
          <link:label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/label" xlink:label="lab_cik0000897421_SwapTransactionsRiskMember" xml:lang="en-US">Swap Transactions Risk [Member]</link:label>
          <link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_cik0000897421_SwapTransactionsRiskMember" xlink:to="lab_cik0000897421_SwapTransactionsRiskMember" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_TaxabilityRiskMember" xlink:label="loc_cik0000897421_TaxabilityRiskMember" />
          <link:label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/label" xlink:label="lab_cik0000897421_TaxabilityRiskMember" xml:lang="en-US">Taxability Risk [Member]</link:label>
          <link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_cik0000897421_TaxabilityRiskMember" xlink:to="lab_cik0000897421_TaxabilityRiskMember" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_TobaccoSettlementBondRiskMember" xlink:label="loc_cik0000897421_TobaccoSettlementBondRiskMember" />
          <link:label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/label" xlink:label="lab_cik0000897421_TobaccoSettlementBondRiskMember" xml:lang="en-US">Tobacco Settlement Bond Risk [Member]</link:label>
          <link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_cik0000897421_TobaccoSettlementBondRiskMember" xlink:to="lab_cik0000897421_TobaccoSettlementBondRiskMember" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_UnratedSecuritiesRiskMember" xlink:label="loc_cik0000897421_UnratedSecuritiesRiskMember" />
          <link:label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/label" xlink:label="lab_cik0000897421_UnratedSecuritiesRiskMember" xml:lang="en-US">Unrated Securities Risk [Member]</link:label>
          <link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_cik0000897421_UnratedSecuritiesRiskMember" xlink:to="lab_cik0000897421_UnratedSecuritiesRiskMember" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_ValuationRiskMember" xlink:label="loc_cik0000897421_ValuationRiskMember" />
          <link:label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/label" xlink:label="lab_cik0000897421_ValuationRiskMember" xml:lang="en-US">Valuation Risk [Member]</link:label>
          <link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_cik0000897421_ValuationRiskMember" xlink:to="lab_cik0000897421_ValuationRiskMember" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_WhenissuedAndDelayeddeliveryTransactionsRiskMember" xlink:label="loc_cik0000897421_WhenissuedAndDelayeddeliveryTransactionsRiskMember" />
          <link:label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/label" xlink:label="lab_cik0000897421_WhenissuedAndDelayeddeliveryTransactionsRiskMember" xml:lang="en-US">When-Issued and Delayed-Delivery Transactions Risk [Member]</link:label>
          <link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_cik0000897421_WhenissuedAndDelayeddeliveryTransactionsRiskMember" xlink:to="lab_cik0000897421_WhenissuedAndDelayeddeliveryTransactionsRiskMember" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_ZeroCouponBondsRiskMember" xlink:label="loc_cik0000897421_ZeroCouponBondsRiskMember" />
          <link:label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/label" xlink:label="lab_cik0000897421_ZeroCouponBondsRiskMember" xml:lang="en-US">Zero Coupon Bonds Risk [Member]</link:label>
          <link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_cik0000897421_ZeroCouponBondsRiskMember" xlink:to="lab_cik0000897421_ZeroCouponBondsRiskMember" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_AntitakeoverProvisionsMember" xlink:label="loc_cik0000897421_AntitakeoverProvisionsMember" />
          <link:label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/label" xlink:label="lab_cik0000897421_AntitakeoverProvisionsMember" xml:lang="en-US">AntiTakeover Provisions [Member]</link:label>
          <link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_cik0000897421_AntitakeoverProvisionsMember" xlink:to="lab_cik0000897421_AntitakeoverProvisionsMember" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_CounterpartyRiskMember" xlink:label="loc_cik0000897421_CounterpartyRiskMember" />
          <link:label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/label" xlink:label="lab_cik0000897421_CounterpartyRiskMember" xml:lang="en-US">Counterparty Risk [Member]</link:label>
          <link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_cik0000897421_CounterpartyRiskMember" xlink:to="lab_cik0000897421_CounterpartyRiskMember" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_CybersecurityRiskMember" xlink:label="loc_cik0000897421_CybersecurityRiskMember" />
          <link:label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/label" xlink:label="lab_cik0000897421_CybersecurityRiskMember" xml:lang="en-US">Cybersecurity Risk [Member]</link:label>
          <link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_cik0000897421_CybersecurityRiskMember" xlink:to="lab_cik0000897421_CybersecurityRiskMember" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_EconomicAndPoliticalEventsRiskMember" xlink:label="loc_cik0000897421_EconomicAndPoliticalEventsRiskMember" />
          <link:label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/label" xlink:label="lab_cik0000897421_EconomicAndPoliticalEventsRiskMember" xml:lang="en-US">Economic and Political Events Risk [Member]</link:label>
          <link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_cik0000897421_EconomicAndPoliticalEventsRiskMember" xlink:to="lab_cik0000897421_EconomicAndPoliticalEventsRiskMember" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_FundTaxRiskMember" xlink:label="loc_cik0000897421_FundTaxRiskMember" />
          <link:label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/label" xlink:label="lab_cik0000897421_FundTaxRiskMember" xml:lang="en-US">Fund Tax Risk [Member]</link:label>
          <link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_cik0000897421_FundTaxRiskMember" xlink:to="lab_cik0000897421_FundTaxRiskMember" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_GlobalEconomicRiskMember" xlink:label="loc_cik0000897421_GlobalEconomicRiskMember" />
          <link:label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/label" xlink:label="lab_cik0000897421_GlobalEconomicRiskMember" xml:lang="en-US">Global Economic Risk [Member]</link:label>
          <link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_cik0000897421_GlobalEconomicRiskMember" xlink:to="lab_cik0000897421_GlobalEconomicRiskMember" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_InvestmentAndMarketRiskMember" xlink:label="loc_cik0000897421_InvestmentAndMarketRiskMember" />
          <link:label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/label" xlink:label="lab_cik0000897421_InvestmentAndMarketRiskMember" xml:lang="en-US">Investment and Market Risk [Member]</link:label>
          <link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_cik0000897421_InvestmentAndMarketRiskMember" xlink:to="lab_cik0000897421_InvestmentAndMarketRiskMember" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_LegislationAndRegulatoryRiskMember" xlink:label="loc_cik0000897421_LegislationAndRegulatoryRiskMember" />
          <link:label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/label" xlink:label="lab_cik0000897421_LegislationAndRegulatoryRiskMember" xml:lang="en-US">Legislation and Regulatory Risk [Member]</link:label>
          <link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_cik0000897421_LegislationAndRegulatoryRiskMember" xlink:to="lab_cik0000897421_LegislationAndRegulatoryRiskMember" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_LeverageRiskMember" xlink:label="loc_cik0000897421_LeverageRiskMember" />
          <link:label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/label" xlink:label="lab_cik0000897421_LeverageRiskMember" xml:lang="en-US">Leverage Risk [Member]</link:label>
          <link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_cik0000897421_LeverageRiskMember" xlink:to="lab_cik0000897421_LeverageRiskMember" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_MarketDiscountFromNetAssetValueMember" xlink:label="loc_cik0000897421_MarketDiscountFromNetAssetValueMember" />
          <link:label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/label" xlink:label="lab_cik0000897421_MarketDiscountFromNetAssetValueMember" xml:lang="en-US">Market Discount from Net Asset Value [Member]</link:label>
          <link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_cik0000897421_MarketDiscountFromNetAssetValueMember" xlink:to="lab_cik0000897421_MarketDiscountFromNetAssetValueMember" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_RecentMarketConditionsMember" xlink:label="loc_cik0000897421_RecentMarketConditionsMember" />
          <link:label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/label" xlink:label="lab_cik0000897421_RecentMarketConditionsMember" xml:lang="en-US">Recent Market Conditions [Member]</link:label>
          <link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_cik0000897421_RecentMarketConditionsMember" xlink:to="lab_cik0000897421_RecentMarketConditionsMember" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_ReverseRepurchaseAgreementRiskMember" xlink:label="loc_cik0000897421_ReverseRepurchaseAgreementRiskMember" />
          <link:label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/label" xlink:label="lab_cik0000897421_ReverseRepurchaseAgreementRiskMember" xml:lang="en-US">Reverse Repurchase Agreement Risk [Member]</link:label>
          <link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_cik0000897421_ReverseRepurchaseAgreementRiskMember" xlink:to="lab_cik0000897421_ReverseRepurchaseAgreementRiskMember" />
          <link:loc xlink:type="locator" xlink:href="cik0000897421-20260531.xsd#cik0000897421_CreditSpreadRiskMember" xlink:label="loc_cik0000897421_CreditSpreadRiskMember" />
          <link:label xlink:type="resource" xlink:role="http://www.xbrl.org/2003/role/label" xlink:label="lab_cik0000897421_CreditSpreadRiskMember" xml:lang="en-US">Credit Spread Risk [Member]</link:label>
          <link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_cik0000897421_CreditSpreadRiskMember" xlink:to="lab_cik0000897421_CreditSpreadRiskMember" />
        </link:labelLink>
      </link:linkbase>
    </appinfo>
  </annotation>
  <import namespace="http://xbrl.sec.gov/cef/2026" schemaLocation="https://xbrl.sec.gov/cef/2026/cef-2026.xsd" />
  <import namespace="http://xbrl.sec.gov/cef-pre/2026" schemaLocation="https://xbrl.sec.gov/cef/2026/cef-2026_pre.xsd" />
  <import namespace="http://www.xbrl.org/2003/instance" schemaLocation="http://www.xbrl.org/2003/xbrl-instance-2003-12-31.xsd" />
  <import namespace="http://xbrl.org/2005/xbrldt" schemaLocation="http://www.xbrl.org/2005/xbrldt-2005.xsd" />
  <import namespace="http://www.xbrl.org/dtr/type/2024-01-31" schemaLocation="https://www.xbrl.org/dtr/type/2024-01-31/types.xsd" />
  <import namespace="http://xbrl.sec.gov/dei/2026" schemaLocation="https://xbrl.sec.gov/dei/2026/dei-2026.xsd" />
  <import namespace="http://www.xbrl.org/2003/linkbase" schemaLocation="http://www.xbrl.org/2003/xbrl-linkbase-2003-12-31.xsd" />
  <import namespace="http://www.xbrl.org/dtr/type/2020-01-21" schemaLocation="https://www.xbrl.org/dtr/type/2020-01-21/types.xsd" />
  <element name="CommonSharesMember" type="dtr-types:domainItemType" abstract="true" xbrli:periodType="duration" nillable="true" id="cik0000897421_CommonSharesMember" substitutionGroup="xbrli:item" />
  <element name="VariableRateDemandPreferredSharesMember" type="dtr-types:domainItemType" abstract="true" xbrli:periodType="duration" nillable="true" id="cik0000897421_VariableRateDemandPreferredSharesMember" substitutionGroup="xbrli:item" />
  <element name="AlternativeMinimumTaxRiskMember" type="dtr-types:domainItemType" abstract="true" xbrli:periodType="duration" nillable="true" id="cik0000897421_AlternativeMinimumTaxRiskMember" substitutionGroup="xbrli:item" />
  <element name="BelowInvestmentGradeRiskMember" type="dtr-types:domainItemType" abstract="true" xbrli:periodType="duration" nillable="true" id="cik0000897421_BelowInvestmentGradeRiskMember" substitutionGroup="xbrli:item" />
  <element name="CallRiskMember" type="dtr-types:domainItemType" abstract="true" xbrli:periodType="duration" nillable="true" id="cik0000897421_CallRiskMember" substitutionGroup="xbrli:item" />
  <element name="CreditRisksMember" type="dtr-types:domainItemType" abstract="true" xbrli:periodType="duration" nillable="true" id="cik0000897421_CreditRisksMember" substitutionGroup="xbrli:item" />
  <element name="CreditSpreadRiskMember" type="dtr-types:domainItemType" abstract="true" xbrli:periodType="duration" nillable="true" id="cik0000897421_CreditSpreadRiskMember" substitutionGroup="xbrli:item" />
  <element name="DefaultedOrDistressedSecuritiesRiskMember" type="dtr-types:domainItemType" abstract="true" xbrli:periodType="duration" nillable="true" id="cik0000897421_DefaultedOrDistressedSecuritiesRiskMember" substitutionGroup="xbrli:item" />
  <element name="DeflationRiskMember" type="dtr-types:domainItemType" abstract="true" xbrli:periodType="duration" nillable="true" id="cik0000897421_DeflationRiskMember" substitutionGroup="xbrli:item" />
  <element name="DurationRiskMember" type="dtr-types:domainItemType" abstract="true" xbrli:periodType="duration" nillable="true" id="cik0000897421_DurationRiskMember" substitutionGroup="xbrli:item" />
  <element name="DerivativesRiskMember" type="dtr-types:domainItemType" abstract="true" xbrli:periodType="duration" nillable="true" id="cik0000897421_DerivativesRiskMember" substitutionGroup="xbrli:item" />
  <element name="EconomicSectorRiskMember" type="dtr-types:domainItemType" abstract="true" xbrli:periodType="duration" nillable="true" id="cik0000897421_EconomicSectorRiskMember" substitutionGroup="xbrli:item" />
  <element name="FinancialFuturesAndOptionsTransactionsRiskMember" type="dtr-types:domainItemType" abstract="true" xbrli:periodType="duration" nillable="true" id="cik0000897421_FinancialFuturesAndOptionsTransactionsRiskMember" substitutionGroup="xbrli:item" />
  <element name="FloatingAndVariableRateSecuritiesRiskMember" type="dtr-types:domainItemType" abstract="true" xbrli:periodType="duration" nillable="true" id="cik0000897421_FloatingAndVariableRateSecuritiesRiskMember" substitutionGroup="xbrli:item" />
  <element name="HedgingRiskMember" type="dtr-types:domainItemType" abstract="true" xbrli:periodType="duration" nillable="true" id="cik0000897421_HedgingRiskMember" substitutionGroup="xbrli:item" />
  <element name="IncomeRiskMember" type="dtr-types:domainItemType" abstract="true" xbrli:periodType="duration" nillable="true" id="cik0000897421_IncomeRiskMember" substitutionGroup="xbrli:item" />
  <element name="InflationRiskMember" type="dtr-types:domainItemType" abstract="true" xbrli:periodType="duration" nillable="true" id="cik0000897421_InflationRiskMember" substitutionGroup="xbrli:item" />
  <element name="InsuranceRiskMember" type="dtr-types:domainItemType" abstract="true" xbrli:periodType="duration" nillable="true" id="cik0000897421_InsuranceRiskMember" substitutionGroup="xbrli:item" />
  <element name="InverseFloatingRateSecuritiesRiskMember" type="dtr-types:domainItemType" abstract="true" xbrli:periodType="duration" nillable="true" id="cik0000897421_InverseFloatingRateSecuritiesRiskMember" substitutionGroup="xbrli:item" />
  <element name="MunicipalSecuritiesRiskMember" type="dtr-types:domainItemType" abstract="true" xbrli:periodType="duration" nillable="true" id="cik0000897421_MunicipalSecuritiesRiskMember" substitutionGroup="xbrli:item" />
  <element name="MunicipalSecuritiesMarketLiquidityRiskMember" type="dtr-types:domainItemType" abstract="true" xbrli:periodType="duration" nillable="true" id="cik0000897421_MunicipalSecuritiesMarketLiquidityRiskMember" substitutionGroup="xbrli:item" />
  <element name="MunicipalSecuritiesMarketRiskMember" type="dtr-types:domainItemType" abstract="true" xbrli:periodType="duration" nillable="true" id="cik0000897421_MunicipalSecuritiesMarketRiskMember" substitutionGroup="xbrli:item" />
  <element name="OtherInvestmentCompaniesRiskMember" type="dtr-types:domainItemType" abstract="true" xbrli:periodType="duration" nillable="true" id="cik0000897421_OtherInvestmentCompaniesRiskMember" substitutionGroup="xbrli:item" />
  <element name="PuertoRicoMunicipalSecuritiesMarketRiskMember" type="dtr-types:domainItemType" abstract="true" xbrli:periodType="duration" nillable="true" id="cik0000897421_PuertoRicoMunicipalSecuritiesMarketRiskMember" substitutionGroup="xbrli:item" />
  <element name="ReinvestmentRiskMember" type="dtr-types:domainItemType" abstract="true" xbrli:periodType="duration" nillable="true" id="cik0000897421_ReinvestmentRiskMember" substitutionGroup="xbrli:item" />
  <element name="RestrictedAndIlliquidInvestmentsRiskMember" type="dtr-types:domainItemType" abstract="true" xbrli:periodType="duration" nillable="true" id="cik0000897421_RestrictedAndIlliquidInvestmentsRiskMember" substitutionGroup="xbrli:item" />
  <element name="SpecialConsiderationsRelatedToSingleStateConcentrationRiskMember" type="dtr-types:domainItemType" abstract="true" xbrli:periodType="duration" nillable="true" id="cik0000897421_SpecialConsiderationsRelatedToSingleStateConcentrationRiskMember" substitutionGroup="xbrli:item" />
  <element name="SpecialRisksRelatedToCertainMunicipalObligationsMember" type="dtr-types:domainItemType" abstract="true" xbrli:periodType="duration" nillable="true" id="cik0000897421_SpecialRisksRelatedToCertainMunicipalObligationsMember" substitutionGroup="xbrli:item" />
  <element name="StructuredProductsRiskMember" type="dtr-types:domainItemType" abstract="true" xbrli:periodType="duration" nillable="true" id="cik0000897421_StructuredProductsRiskMember" substitutionGroup="xbrli:item" />
  <element name="SwapTransactionsRiskMember" type="dtr-types:domainItemType" abstract="true" xbrli:periodType="duration" nillable="true" id="cik0000897421_SwapTransactionsRiskMember" substitutionGroup="xbrli:item" />
  <element name="TaxRiskMember" type="dtr-types:domainItemType" abstract="true" xbrli:periodType="duration" nillable="true" id="cik0000897421_TaxRiskMember" substitutionGroup="xbrli:item" />
  <element name="TaxabilityRiskMember" type="dtr-types:domainItemType" abstract="true" xbrli:periodType="duration" nillable="true" id="cik0000897421_TaxabilityRiskMember" substitutionGroup="xbrli:item" />
  <element name="TobaccoSettlementBondRiskMember" type="dtr-types:domainItemType" abstract="true" xbrli:periodType="duration" nillable="true" id="cik0000897421_TobaccoSettlementBondRiskMember" substitutionGroup="xbrli:item" />
  <element name="UnratedSecuritiesRiskMember" type="dtr-types:domainItemType" abstract="true" xbrli:periodType="duration" nillable="true" id="cik0000897421_UnratedSecuritiesRiskMember" substitutionGroup="xbrli:item" />
  <element name="ValuationRiskMember" type="dtr-types:domainItemType" abstract="true" xbrli:periodType="duration" nillable="true" id="cik0000897421_ValuationRiskMember" substitutionGroup="xbrli:item" />
  <element name="WhenissuedAndDelayeddeliveryTransactionsRiskMember" type="dtr-types:domainItemType" abstract="true" xbrli:periodType="duration" nillable="true" id="cik0000897421_WhenissuedAndDelayeddeliveryTransactionsRiskMember" substitutionGroup="xbrli:item" />
  <element name="ZeroCouponBondsRiskMember" type="dtr-types:domainItemType" abstract="true" xbrli:periodType="duration" nillable="true" id="cik0000897421_ZeroCouponBondsRiskMember" substitutionGroup="xbrli:item" />
  <element name="AntitakeoverProvisionsMember" type="dtr-types:domainItemType" abstract="true" xbrli:periodType="duration" nillable="true" id="cik0000897421_AntitakeoverProvisionsMember" substitutionGroup="xbrli:item" />
  <element name="CounterpartyRiskMember" type="dtr-types:domainItemType" abstract="true" xbrli:periodType="duration" nillable="true" id="cik0000897421_CounterpartyRiskMember" substitutionGroup="xbrli:item" />
  <element name="CybersecurityRiskMember" type="dtr-types:domainItemType" abstract="true" xbrli:periodType="duration" nillable="true" id="cik0000897421_CybersecurityRiskMember" substitutionGroup="xbrli:item" />
  <element name="EconomicAndPoliticalEventsRiskMember" type="dtr-types:domainItemType" abstract="true" xbrli:periodType="duration" nillable="true" id="cik0000897421_EconomicAndPoliticalEventsRiskMember" substitutionGroup="xbrli:item" />
  <element name="FundTaxRiskMember" type="dtr-types:domainItemType" abstract="true" xbrli:periodType="duration" nillable="true" id="cik0000897421_FundTaxRiskMember" substitutionGroup="xbrli:item" />
  <element name="GlobalEconomicRiskMember" type="dtr-types:domainItemType" abstract="true" xbrli:periodType="duration" nillable="true" id="cik0000897421_GlobalEconomicRiskMember" substitutionGroup="xbrli:item" />
  <element name="InvestmentAndMarketRiskMember" type="dtr-types:domainItemType" abstract="true" xbrli:periodType="duration" nillable="true" id="cik0000897421_InvestmentAndMarketRiskMember" substitutionGroup="xbrli:item" />
  <element name="LegislationAndRegulatoryRiskMember" type="dtr-types:domainItemType" abstract="true" xbrli:periodType="duration" nillable="true" id="cik0000897421_LegislationAndRegulatoryRiskMember" substitutionGroup="xbrli:item" />
  <element name="LeverageRiskMember" type="dtr-types:domainItemType" abstract="true" xbrli:periodType="duration" nillable="true" id="cik0000897421_LeverageRiskMember" substitutionGroup="xbrli:item" />
  <element name="MarketDiscountFromNetAssetValueMember" type="dtr-types:domainItemType" abstract="true" xbrli:periodType="duration" nillable="true" id="cik0000897421_MarketDiscountFromNetAssetValueMember" substitutionGroup="xbrli:item" />
  <element name="RecentMarketConditionsMember" type="dtr-types:domainItemType" abstract="true" xbrli:periodType="duration" nillable="true" id="cik0000897421_RecentMarketConditionsMember" substitutionGroup="xbrli:item" />
  <element name="ReverseRepurchaseAgreementRiskMember" type="dtr-types:domainItemType" abstract="true" xbrli:periodType="duration" nillable="true" id="cik0000897421_ReverseRepurchaseAgreementRiskMember" substitutionGroup="xbrli:item" />
</schema>
