<?xml version='1.0' encoding='US-ASCII'?><schema xmlns="http://www.w3.org/2001/XMLSchema" xmlns:dws="http://dws/20260531" xmlns:dei="http://xbrl.sec.gov/dei/2025" xmlns:srt-types="http://fasb.org/srt-types/2025" xmlns:deprecated="http://www.xbrl.org/2009/role/deprecated" xmlns:dtr="http://www.xbrl.org/2009/dtr" xmlns:oef="http://xbrl.sec.gov/oef/2025" xmlns:ref="http://www.xbrl.org/2006/ref" xmlns:xbrldt="http://xbrl.org/2005/xbrldt" xmlns:xl="http://www.xbrl.org/2003/XLink" xmlns:us-gaap="http://fasb.org/us-gaap/2025" xmlns:oef-pre="http://xbrl.sec.gov/oef-pre/2025" xmlns:oef-lab="http://xbrl.sec.gov/oef-lab/2025" xmlns:link="http://www.xbrl.org/2003/linkbase" xmlns:country="http://xbrl.sec.gov/country/2025" xmlns:us-roles="http://fasb.org/us-roles/2025" xmlns:enum2="http://xbrl.org/2020/extensible-enumerations-2.0" xmlns:us-types="http://fasb.org/us-types/2025" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:dtr-types="http://www.xbrl.org/dtr/type/2022-03-31" xmlns:oef-def="http://xbrl.sec.gov/oef-def/2025" xmlns:negated="http://www.xbrl.org/2009/role/negated" xmlns:xbrldi="http://xbrl.org/2006/xbrldi" xmlns:srt="http://fasb.org/srt/2025" xmlns:oef-sr="http://xbrl.sec.gov/oef-sr/2025" xmlns:srt-roles="http://fasb.org/srt-roles/2025" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns:xbrli="http://www.xbrl.org/2003/instance" targetNamespace="http://dws/20260531" elementFormDefault="qualified"><import namespace="http://www.xbrl.org/2003/instance" schemaLocation="http://www.xbrl.org/2003/xbrl-instance-2003-12-31.xsd"/><import namespace="http://www.xbrl.org/2003/linkbase" schemaLocation="http://www.xbrl.org/2003/xbrl-linkbase-2003-12-31.xsd"/><import namespace="http://xbrl.sec.gov/dei/2025" schemaLocation="https://xbrl.sec.gov/dei/2025/dei-2025.xsd"/><import namespace="http://fasb.org/us-types/2025" schemaLocation="https://xbrl.fasb.org/us-gaap/2025/elts/us-types-2025.xsd"/><import namespace="http://www.xbrl.org/dtr/type/2022-03-31" schemaLocation="https://www.xbrl.org/dtr/type/2022-03-31/types.xsd"/><import namespace="http://xbrl.sec.gov/country/2025" schemaLocation="https://xbrl.sec.gov/country/2025/country-2025.xsd"/><import namespace="http://fasb.org/srt/2025" schemaLocation="https://xbrl.fasb.org/srt/2025/elts/srt-2025.xsd"/><import namespace="http://fasb.org/srt-types/2025" schemaLocation="https://xbrl.fasb.org/srt/2025/elts/srt-types-2025.xsd"/><import namespace="http://xbrl.sec.gov/oef-sr/2025" schemaLocation="https://xbrl.sec.gov/oef/2025/oef-sr-2025.xsd"/><import namespace="http://fasb.org/us-gaap/2025" schemaLocation="https://xbrl.fasb.org/us-gaap/2025/elts/us-gaap-2025.xsd"/><import namespace="http://fasb.org/us-roles/2025" schemaLocation="https://xbrl.fasb.org/us-gaap/2025/elts/us-roles-2025.xsd"/><import namespace="http://fasb.org/srt-roles/2025" schemaLocation="https://xbrl.fasb.org/srt/2025/elts/srt-roles-2025.xsd"/><annotation><appinfo><link:linkbase id="lnk"><link:arcroleRef arcroleURI="http://xbrl.org/int/dim/arcrole/domain-member" xlink:type="simple" xlink:href="http://www.xbrl.org/2005/xbrldt-2005.xsd#domain-member"/><link:roleRef roleURI="http://xbrl.sec.gov/oef/role/ShareholderReport" xlink:type="simple" xlink:href="https://xbrl.sec.gov/oef/2025/oef-2025.xsd#ShareholderReport"/><link:roleRef roleURI="http://xbrl.sec.gov/oef/role/ShareholderReportHoldingsDetails" xlink:type="simple" xlink:href="https://xbrl.sec.gov/oef/2025/oef-2025.xsd#ShareholderReportHoldingsDetails"/><link:roleRef roleURI="http://xbrl.sec.gov/oef/role/ShareholderReportLineGraphDetails" xlink:type="simple" xlink:href="https://xbrl.sec.gov/oef/2025/oef-2025.xsd#ShareholderReportLineGraphDetails"/><link:roleRef roleURI="http://xbrl.sec.gov/oef/role/ShareholderReportAverageAnnualReturnDetails" xlink:type="simple" xlink:href="https://xbrl.sec.gov/oef/2025/oef-2025.xsd#ShareholderReportAverageAnnualReturnDetails"/><link:roleRef roleURI="http://xbrl.sec.gov/oef/role/ClassOnly" xlink:type="simple" xlink:href="https://xbrl.sec.gov/oef/2025/oef-2025.xsd#ClassOnly"/><link:roleRef roleURI="http://xbrl.sec.gov/oef/role/BroadBasedIndexOnly" xlink:type="simple" xlink:href="https://xbrl.sec.gov/oef/2025/oef-2025.xsd#BroadBasedIndexOnly"/><link:roleRef roleURI="http://fasb.org/us-gaap/role/eedm/ExtensibleEnumerationLists" xlink:type="simple" xlink:href="https://xbrl.fasb.org/us-gaap/2025/elts/us-roles-2025.xsd#eedm"/><link:roleRef roleURI="http://xbrl.sec.gov/oef/role/Other1CategoryOnly" xlink:type="simple" xlink:href="https://xbrl.sec.gov/oef/2025/oef-2025.xsd#Other1CategoryOnly"/><link:roleRef roleURI="http://xbrl.sec.gov/oef/role/LargestHoldingOnly" xlink:type="simple" xlink:href="https://xbrl.sec.gov/oef/2025/oef-2025.xsd#LargestHoldingOnly"/><link:presentationLink xlink:type="extended" xlink:role="http://xbrl.sec.gov/oef/role/ShareholderReport"><link:loc xlink:type="locator" xlink:href="https://xbrl.sec.gov/oef/2025/oef-2025.xsd#oef_ShareClassDomain" xlink:label="ShareClassDomain"/><link:loc xlink:type="locator" xlink:href="#dws_C000016740Member" xlink:label="C000016740Member"/><link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="ShareClassDomain" xlink:to="C000016740Member" order="1.0" preferredLabel="http://www.xbrl.org/2003/role/label" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_C000016743Member" xlink:label="C000016743Member"/><link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="ShareClassDomain" xlink:to="C000016743Member" order="2.0" preferredLabel="http://www.xbrl.org/2003/role/label" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_C000016744Member" xlink:label="C000016744Member"/><link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="ShareClassDomain" xlink:to="C000016744Member" order="3.0" preferredLabel="http://www.xbrl.org/2003/role/label" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_C000016745Member" xlink:label="C000016745Member"/><link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="ShareClassDomain" xlink:to="C000016745Member" order="4.0" preferredLabel="http://www.xbrl.org/2003/role/label" priority="1"/></link:presentationLink><link:presentationLink xlink:type="extended" xlink:role="http://xbrl.sec.gov/oef/role/ShareholderReportHoldingsDetails"><link:loc xlink:type="locator" xlink:href="https://xbrl.sec.gov/oef/2025/oef-2025.xsd#oef_ShareClassDomain" xlink:label="ShareClassDomain"/><link:loc xlink:type="locator" xlink:href="#dws_C000016740Member" xlink:label="C000016740Member"/><link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="ShareClassDomain" xlink:to="C000016740Member" order="1.0" preferredLabel="http://www.xbrl.org/2003/role/label" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_C000016743Member" xlink:label="C000016743Member"/><link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="ShareClassDomain" xlink:to="C000016743Member" order="2.0" preferredLabel="http://www.xbrl.org/2003/role/label" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_C000016744Member" xlink:label="C000016744Member"/><link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="ShareClassDomain" xlink:to="C000016744Member" order="3.0" preferredLabel="http://www.xbrl.org/2003/role/label" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_C000016745Member" xlink:label="C000016745Member"/><link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="ShareClassDomain" xlink:to="C000016745Member" order="4.0" preferredLabel="http://www.xbrl.org/2003/role/label" priority="1"/><link:loc xlink:type="locator" xlink:href="https://xbrl.sec.gov/oef/2025/oef-2025.xsd#oef_LargestHoldingsDomain" xlink:label="LargestHoldingsDomain"/><link:loc xlink:type="locator" xlink:href="#dws_TexasCTIMember" xlink:label="TexasCTIMember"/><link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="LargestHoldingsDomain" xlink:to="TexasCTIMember" order="1.0" preferredLabel="http://www.xbrl.org/2003/role/label" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_NewYorkCTIMember" xlink:label="NewYorkCTIMember"/><link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="LargestHoldingsDomain" xlink:to="NewYorkCTIMember" order="2.0" preferredLabel="http://www.xbrl.org/2003/role/label" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_FloridaCTIMember" xlink:label="FloridaCTIMember"/><link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="LargestHoldingsDomain" xlink:to="FloridaCTIMember" order="3.0" preferredLabel="http://www.xbrl.org/2003/role/label" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_IllinoisCTIMember" xlink:label="IllinoisCTIMember"/><link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="LargestHoldingsDomain" xlink:to="IllinoisCTIMember" order="4.0" preferredLabel="http://www.xbrl.org/2003/role/label" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_WisconsinCTIMember" xlink:label="WisconsinCTIMember"/><link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="LargestHoldingsDomain" xlink:to="WisconsinCTIMember" order="5.0" preferredLabel="http://www.xbrl.org/2003/role/label" priority="1"/><link:loc xlink:type="locator" xlink:href="https://xbrl.fasb.org/us-gaap/2025/elts/us-gaap-2025.xsd#us-gaap_InvestmentTypeCategorizationMember" xlink:label="InvestmentTypeCategorizationMember"/><link:loc xlink:type="locator" xlink:href="#dws_RevenueBondsCTIMember" xlink:label="RevenueBondsCTIMember"/><link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="InvestmentTypeCategorizationMember" xlink:to="RevenueBondsCTIMember" order="1.0" preferredLabel="http://www.xbrl.org/2003/role/label" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_GeneralObligationBondsCTIMember" xlink:label="GeneralObligationBondsCTIMember"/><link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="InvestmentTypeCategorizationMember" xlink:to="GeneralObligationBondsCTIMember" order="2.0" preferredLabel="http://www.xbrl.org/2003/role/label" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_LeaseObligationsCTIMember" xlink:label="LeaseObligationsCTIMember"/><link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="InvestmentTypeCategorizationMember" xlink:to="LeaseObligationsCTIMember" order="3.0" preferredLabel="http://www.xbrl.org/2003/role/label" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_VariableRateDemandNotesCTIMember" xlink:label="VariableRateDemandNotesCTIMember"/><link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="InvestmentTypeCategorizationMember" xlink:to="VariableRateDemandNotesCTIMember" order="4.0" preferredLabel="http://www.xbrl.org/2003/role/label" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_EscrowtoMaturityPrerefundedBondsCTIMember" xlink:label="EscrowtoMaturityPrerefundedBondsCTIMember"/><link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="InvestmentTypeCategorizationMember" xlink:to="EscrowtoMaturityPrerefundedBondsCTIMember" order="5.0" preferredLabel="http://www.xbrl.org/2003/role/label" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_OtherCTIMember" xlink:label="OtherCTIMember"/><link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="InvestmentTypeCategorizationMember" xlink:to="OtherCTIMember" order="6.0" preferredLabel="http://www.xbrl.org/2003/role/label" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_OtherAssetsandLiabilitiesNetCTIMember" xlink:label="OtherAssetsandLiabilitiesNetCTIMember"/><link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="InvestmentTypeCategorizationMember" xlink:to="OtherAssetsandLiabilitiesNetCTIMember" order="7.0" preferredLabel="http://www.xbrl.org/2003/role/label" priority="1"/><link:loc xlink:type="locator" xlink:href="https://xbrl.sec.gov/oef/2025/oef-2025.xsd#oef_OtherCategory1Domain" xlink:label="OtherCategory1Domain"/><link:loc xlink:type="locator" xlink:href="#dws_NRCTIMember" xlink:label="NRCTIMember"/><link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="OtherCategory1Domain" xlink:to="NRCTIMember" order="1.0" preferredLabel="http://www.xbrl.org/2003/role/label" priority="1"/><link:loc xlink:type="locator" xlink:href="https://xbrl.sec.gov/oef/2025/oef-2025.xsd#oef_CreditQualityDomain" xlink:label="CreditQualityDomain"/><link:loc xlink:type="locator" xlink:href="https://xbrl.fasb.org/srt/2025/elts/srt-2025.xsd#srt_StandardPoorsAAARatingMember" xlink:label="StandardPoorsAAARatingMember"/><link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="CreditQualityDomain" xlink:to="StandardPoorsAAARatingMember" order="1.0" preferredLabel="http://www.xbrl.org/2003/role/label" priority="1"/><link:loc xlink:type="locator" xlink:href="https://xbrl.fasb.org/srt/2025/elts/srt-2025.xsd#srt_StandardPoorsAARatingMember" xlink:label="StandardPoorsAARatingMember"/><link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="CreditQualityDomain" xlink:to="StandardPoorsAARatingMember" order="2.0" preferredLabel="http://www.xbrl.org/2003/role/label" priority="1"/><link:loc xlink:type="locator" xlink:href="https://xbrl.fasb.org/srt/2025/elts/srt-2025.xsd#srt_StandardPoorsARatingMember" xlink:label="StandardPoorsARatingMember"/><link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="CreditQualityDomain" xlink:to="StandardPoorsARatingMember" order="3.0" preferredLabel="http://www.xbrl.org/2003/role/label" priority="1"/><link:loc xlink:type="locator" xlink:href="https://xbrl.fasb.org/srt/2025/elts/srt-2025.xsd#srt_StandardPoorsBBBRatingMember" xlink:label="StandardPoorsBBBRatingMember"/><link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="CreditQualityDomain" xlink:to="StandardPoorsBBBRatingMember" order="4.0" preferredLabel="http://www.xbrl.org/2003/role/label" priority="1"/><link:loc xlink:type="locator" xlink:href="https://xbrl.fasb.org/srt/2025/elts/srt-2025.xsd#srt_StandardPoorsBBRatingMember" xlink:label="StandardPoorsBBRatingMember"/><link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="CreditQualityDomain" xlink:to="StandardPoorsBBRatingMember" order="5.0" preferredLabel="http://www.xbrl.org/2003/role/label" priority="1"/><link:loc xlink:type="locator" xlink:href="https://xbrl.fasb.org/srt/2025/elts/srt-2025.xsd#srt_StandardPoorsBRatingMember" xlink:label="StandardPoorsBRatingMember"/><link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="CreditQualityDomain" xlink:to="StandardPoorsBRatingMember" order="6.0" preferredLabel="http://www.xbrl.org/2003/role/label" priority="1"/><link:loc xlink:type="locator" xlink:href="https://xbrl.fasb.org/srt/2025/elts/srt-2025.xsd#srt_StandardPoorsCCCRatingMember" xlink:label="StandardPoorsCCCRatingMember"/><link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="CreditQualityDomain" xlink:to="StandardPoorsCCCRatingMember" order="7.0" preferredLabel="http://www.xbrl.org/2003/role/label" priority="1"/><link:loc xlink:type="locator" xlink:href="https://xbrl.fasb.org/srt/2025/elts/srt-2025.xsd#srt_StandardPoorsCCRatingMember" xlink:label="StandardPoorsCCRatingMember"/><link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="CreditQualityDomain" xlink:to="StandardPoorsCCRatingMember" order="8.0" preferredLabel="http://www.xbrl.org/2003/role/label" priority="1"/></link:presentationLink><link:presentationLink xlink:type="extended" xlink:role="http://xbrl.sec.gov/oef/role/ShareholderReportLineGraphDetails"><link:loc xlink:type="locator" xlink:href="https://xbrl.sec.gov/oef/2025/oef-2025.xsd#oef_ShareClassDomain" xlink:label="ShareClassDomain"/><link:loc xlink:type="locator" xlink:href="#dws_C000016740Member" xlink:label="C000016740Member"/><link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="ShareClassDomain" xlink:to="C000016740Member" order="1.0" preferredLabel="http://www.xbrl.org/2003/role/label" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_C000016743Member" xlink:label="C000016743Member"/><link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="ShareClassDomain" xlink:to="C000016743Member" order="2.0" preferredLabel="http://www.xbrl.org/2003/role/label" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_C000016744Member" xlink:label="C000016744Member"/><link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="ShareClassDomain" xlink:to="C000016744Member" order="3.0" preferredLabel="http://www.xbrl.org/2003/role/label" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_C000016745Member" xlink:label="C000016745Member"/><link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="ShareClassDomain" xlink:to="C000016745Member" order="4.0" preferredLabel="http://www.xbrl.org/2003/role/label" priority="1"/><link:loc xlink:type="locator" xlink:href="https://xbrl.sec.gov/oef/2025/oef-2025.xsd#oef_BroadBasedIndexDomain" xlink:label="BroadBasedIndexDomain"/><link:loc xlink:type="locator" xlink:href="#dws_DWSIndexBloombergMunicipalBondIndex18675BroadBasedIndexMember" xlink:label="DWSIndexBloombergMunicipalBondIndex18675BroadBasedIndexMember"/><link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="BroadBasedIndexDomain" xlink:to="DWSIndexBloombergMunicipalBondIndex18675BroadBasedIndexMember" order="1.0" preferredLabel="http://www.xbrl.org/2003/role/terseLabel" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_DWSIndexBloombergMunicipalBondIndex18673BroadBasedIndexMember" xlink:label="DWSIndexBloombergMunicipalBondIndex18673BroadBasedIndexMember"/><link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="BroadBasedIndexDomain" xlink:to="DWSIndexBloombergMunicipalBondIndex18673BroadBasedIndexMember" order="2.0" preferredLabel="http://www.xbrl.org/2003/role/terseLabel" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_DWSIndexBloombergMunicipalBondIndex18674BroadBasedIndexMember" xlink:label="DWSIndexBloombergMunicipalBondIndex18674BroadBasedIndexMember"/><link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="BroadBasedIndexDomain" xlink:to="DWSIndexBloombergMunicipalBondIndex18674BroadBasedIndexMember" order="3.0" preferredLabel="http://www.xbrl.org/2003/role/terseLabel" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_DWSIndexBloombergMunicipalBondIndex18676BroadBasedIndexMember" xlink:label="DWSIndexBloombergMunicipalBondIndex18676BroadBasedIndexMember"/><link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="BroadBasedIndexDomain" xlink:to="DWSIndexBloombergMunicipalBondIndex18676BroadBasedIndexMember" order="4.0" preferredLabel="http://www.xbrl.org/2003/role/terseLabel" priority="1"/></link:presentationLink><link:presentationLink xlink:type="extended" xlink:role="http://xbrl.sec.gov/oef/role/ShareholderReportAverageAnnualReturnDetails"><link:loc xlink:type="locator" xlink:href="https://xbrl.sec.gov/oef/2025/oef-2025.xsd#oef_ShareClassDomain" xlink:label="ShareClassDomain"/><link:loc xlink:type="locator" xlink:href="#dws_C000016740Member" xlink:label="C000016740Member"/><link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="ShareClassDomain" xlink:to="C000016740Member" order="1.0" preferredLabel="http://www.xbrl.org/2003/role/label" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_C000016743Member" xlink:label="C000016743Member"/><link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="ShareClassDomain" xlink:to="C000016743Member" order="2.0" preferredLabel="http://www.xbrl.org/2003/role/label" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_C000016744Member" xlink:label="C000016744Member"/><link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="ShareClassDomain" xlink:to="C000016744Member" order="3.0" preferredLabel="http://www.xbrl.org/2003/role/label" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_C000016745Member" xlink:label="C000016745Member"/><link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="ShareClassDomain" xlink:to="C000016745Member" order="4.0" preferredLabel="http://www.xbrl.org/2003/role/label" priority="1"/><link:loc xlink:type="locator" xlink:href="https://xbrl.sec.gov/oef/2025/oef-2025.xsd#oef_BroadBasedIndexDomain" xlink:label="BroadBasedIndexDomain"/><link:loc xlink:type="locator" xlink:href="#dws_DWSIndexBloombergMunicipalBondIndex18675BroadBasedIndexMember" xlink:label="DWSIndexBloombergMunicipalBondIndex18675BroadBasedIndexMember"/><link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="BroadBasedIndexDomain" xlink:to="DWSIndexBloombergMunicipalBondIndex18675BroadBasedIndexMember" order="1.0" preferredLabel="http://www.xbrl.org/2003/role/terseLabel" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_DWSIndexBloombergMunicipalBondIndex18673BroadBasedIndexMember" xlink:label="DWSIndexBloombergMunicipalBondIndex18673BroadBasedIndexMember"/><link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="BroadBasedIndexDomain" xlink:to="DWSIndexBloombergMunicipalBondIndex18673BroadBasedIndexMember" order="2.0" preferredLabel="http://www.xbrl.org/2003/role/terseLabel" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_DWSIndexBloombergMunicipalBondIndex18674BroadBasedIndexMember" xlink:label="DWSIndexBloombergMunicipalBondIndex18674BroadBasedIndexMember"/><link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="BroadBasedIndexDomain" xlink:to="DWSIndexBloombergMunicipalBondIndex18674BroadBasedIndexMember" order="3.0" preferredLabel="http://www.xbrl.org/2003/role/terseLabel" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_DWSIndexBloombergMunicipalBondIndex18676BroadBasedIndexMember" xlink:label="DWSIndexBloombergMunicipalBondIndex18676BroadBasedIndexMember"/><link:presentationArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="BroadBasedIndexDomain" xlink:to="DWSIndexBloombergMunicipalBondIndex18676BroadBasedIndexMember" order="4.0" preferredLabel="http://www.xbrl.org/2003/role/terseLabel" priority="1"/></link:presentationLink><link:definitionLink xlink:type="extended" xlink:role="http://xbrl.sec.gov/oef/role/ClassOnly"><link:loc xlink:type="locator" xlink:href="https://xbrl.sec.gov/oef/2025/oef-2025.xsd#oef_ShareClassDomain" xlink:label="ShareClassDomain"/><link:loc xlink:type="locator" xlink:href="#dws_C000016740Member" xlink:label="C000016740Member"/><link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="ShareClassDomain" xlink:to="C000016740Member" order="1.0" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_C000016743Member" xlink:label="C000016743Member"/><link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="ShareClassDomain" xlink:to="C000016743Member" order="2.0" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_C000016744Member" xlink:label="C000016744Member"/><link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="ShareClassDomain" xlink:to="C000016744Member" order="3.0" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_C000016745Member" xlink:label="C000016745Member"/><link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="ShareClassDomain" xlink:to="C000016745Member" order="4.0" priority="1"/></link:definitionLink><link:definitionLink xlink:type="extended" xlink:role="http://xbrl.sec.gov/oef/role/BroadBasedIndexOnly"><link:loc xlink:type="locator" xlink:href="https://xbrl.sec.gov/oef/2025/oef-2025.xsd#oef_BroadBasedIndexDomain" xlink:label="BroadBasedIndexDomain"/><link:loc xlink:type="locator" xlink:href="#dws_DWSIndexBloombergMunicipalBondIndex18675BroadBasedIndexMember" xlink:label="DWSIndexBloombergMunicipalBondIndex18675BroadBasedIndexMember"/><link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="BroadBasedIndexDomain" xlink:to="DWSIndexBloombergMunicipalBondIndex18675BroadBasedIndexMember" order="1.0" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_DWSIndexBloombergMunicipalBondIndex18673BroadBasedIndexMember" xlink:label="DWSIndexBloombergMunicipalBondIndex18673BroadBasedIndexMember"/><link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="BroadBasedIndexDomain" xlink:to="DWSIndexBloombergMunicipalBondIndex18673BroadBasedIndexMember" order="2.0" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_DWSIndexBloombergMunicipalBondIndex18674BroadBasedIndexMember" xlink:label="DWSIndexBloombergMunicipalBondIndex18674BroadBasedIndexMember"/><link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="BroadBasedIndexDomain" xlink:to="DWSIndexBloombergMunicipalBondIndex18674BroadBasedIndexMember" order="3.0" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_DWSIndexBloombergMunicipalBondIndex18676BroadBasedIndexMember" xlink:label="DWSIndexBloombergMunicipalBondIndex18676BroadBasedIndexMember"/><link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="BroadBasedIndexDomain" xlink:to="DWSIndexBloombergMunicipalBondIndex18676BroadBasedIndexMember" order="4.0" priority="1"/></link:definitionLink><link:definitionLink xlink:type="extended" xlink:role="http://fasb.org/us-gaap/role/eedm/ExtensibleEnumerationLists"><link:loc xlink:type="locator" xlink:href="https://xbrl.fasb.org/us-gaap/2025/elts/us-gaap-2025.xsd#us-gaap_InvestmentTypeCategorizationMember" xlink:label="InvestmentTypeCategorizationMember"/><link:loc xlink:type="locator" xlink:href="#dws_RevenueBondsCTIMember" xlink:label="RevenueBondsCTIMember"/><link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="InvestmentTypeCategorizationMember" xlink:to="RevenueBondsCTIMember" order="1.0" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_GeneralObligationBondsCTIMember" xlink:label="GeneralObligationBondsCTIMember"/><link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="InvestmentTypeCategorizationMember" xlink:to="GeneralObligationBondsCTIMember" order="2.0" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_LeaseObligationsCTIMember" xlink:label="LeaseObligationsCTIMember"/><link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="InvestmentTypeCategorizationMember" xlink:to="LeaseObligationsCTIMember" order="3.0" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_VariableRateDemandNotesCTIMember" xlink:label="VariableRateDemandNotesCTIMember"/><link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="InvestmentTypeCategorizationMember" xlink:to="VariableRateDemandNotesCTIMember" order="4.0" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_EscrowtoMaturityPrerefundedBondsCTIMember" xlink:label="EscrowtoMaturityPrerefundedBondsCTIMember"/><link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="InvestmentTypeCategorizationMember" xlink:to="EscrowtoMaturityPrerefundedBondsCTIMember" order="5.0" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_OtherCTIMember" xlink:label="OtherCTIMember"/><link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="InvestmentTypeCategorizationMember" xlink:to="OtherCTIMember" order="6.0" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_OtherAssetsandLiabilitiesNetCTIMember" xlink:label="OtherAssetsandLiabilitiesNetCTIMember"/><link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="InvestmentTypeCategorizationMember" xlink:to="OtherAssetsandLiabilitiesNetCTIMember" order="7.0" priority="1"/></link:definitionLink><link:definitionLink xlink:type="extended" xlink:role="http://xbrl.sec.gov/oef/role/Other1CategoryOnly"><link:loc xlink:type="locator" xlink:href="https://xbrl.sec.gov/oef/2025/oef-2025.xsd#oef_OtherCategory1Domain" xlink:label="OtherCategory1Domain"/><link:loc xlink:type="locator" xlink:href="#dws_NRCTIMember" xlink:label="NRCTIMember"/><link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="OtherCategory1Domain" xlink:to="NRCTIMember" order="1.0" priority="1"/></link:definitionLink><link:definitionLink xlink:type="extended" xlink:role="http://xbrl.sec.gov/oef/role/LargestHoldingOnly"><link:loc xlink:type="locator" xlink:href="https://xbrl.sec.gov/oef/2025/oef-2025.xsd#oef_LargestHoldingsDomain" xlink:label="LargestHoldingsDomain"/><link:loc xlink:type="locator" xlink:href="#dws_TexasCTIMember" xlink:label="TexasCTIMember"/><link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="LargestHoldingsDomain" xlink:to="TexasCTIMember" order="1.0" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_NewYorkCTIMember" xlink:label="NewYorkCTIMember"/><link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="LargestHoldingsDomain" xlink:to="NewYorkCTIMember" order="2.0" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_FloridaCTIMember" xlink:label="FloridaCTIMember"/><link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="LargestHoldingsDomain" xlink:to="FloridaCTIMember" order="3.0" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_IllinoisCTIMember" xlink:label="IllinoisCTIMember"/><link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="LargestHoldingsDomain" xlink:to="IllinoisCTIMember" order="4.0" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_WisconsinCTIMember" xlink:label="WisconsinCTIMember"/><link:definitionArc xlink:type="arc" xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="LargestHoldingsDomain" xlink:to="WisconsinCTIMember" order="5.0" priority="1"/></link:definitionLink><link:labelLink xlink:type="extended" xlink:role="http://www.xbrl.org/2003/role/link"><link:loc xlink:type="locator" xlink:href="#dws_C000016740Member" xlink:label="C000016740Member"/><link:label xlink:type="resource" xlink:label="label_C000016740Member" xlink:role="http://www.xbrl.org/2003/role/label" xml:lang="en-US">C000016740</link:label><link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="C000016740Member" xlink:to="label_C000016740Member" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_C000016743Member" xlink:label="C000016743Member"/><link:label xlink:type="resource" xlink:label="label_C000016743Member" xlink:role="http://www.xbrl.org/2003/role/label" xml:lang="en-US">C000016743</link:label><link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="C000016743Member" xlink:to="label_C000016743Member" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_C000016744Member" xlink:label="C000016744Member"/><link:label xlink:type="resource" xlink:label="label_C000016744Member" xlink:role="http://www.xbrl.org/2003/role/label" xml:lang="en-US">C000016744</link:label><link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="C000016744Member" xlink:to="label_C000016744Member" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_C000016745Member" xlink:label="C000016745Member"/><link:label xlink:type="resource" xlink:label="label_C000016745Member" xlink:role="http://www.xbrl.org/2003/role/label" xml:lang="en-US">C000016745</link:label><link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="C000016745Member" xlink:to="label_C000016745Member" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_DWSIndexBloombergMunicipalBondIndex18675BroadBasedIndexMember" xlink:label="DWSIndexBloombergMunicipalBondIndex18675BroadBasedIndexMember"/><link:label xlink:type="resource" xlink:label="label_DWSIndexBloombergMunicipalBondIndex18675BroadBasedIndexMember" xlink:role="http://www.xbrl.org/2003/role/terseLabel" xml:lang="en-US">DWS Index: Bloomberg Municipal Bond Index</link:label><link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="DWSIndexBloombergMunicipalBondIndex18675BroadBasedIndexMember" xlink:to="label_DWSIndexBloombergMunicipalBondIndex18675BroadBasedIndexMember" priority="1"/><link:label xlink:type="resource" xlink:label="label_DWSIndexBloombergMunicipalBondIndex18675BroadBasedIndexMember_18675" xlink:role="http://www.xbrl.org/2003/role/label" xml:lang="en-US">DWS Index: Bloomberg Municipal Bond Index_18675</link:label><link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="DWSIndexBloombergMunicipalBondIndex18675BroadBasedIndexMember" xlink:to="label_DWSIndexBloombergMunicipalBondIndex18675BroadBasedIndexMember_18675" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_DWSIndexBloombergMunicipalBondIndex18673BroadBasedIndexMember" xlink:label="DWSIndexBloombergMunicipalBondIndex18673BroadBasedIndexMember"/><link:label xlink:type="resource" xlink:label="label_DWSIndexBloombergMunicipalBondIndex18673BroadBasedIndexMember" xlink:role="http://www.xbrl.org/2003/role/terseLabel" xml:lang="en-US">DWS Index: Bloomberg Municipal Bond Index</link:label><link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="DWSIndexBloombergMunicipalBondIndex18673BroadBasedIndexMember" xlink:to="label_DWSIndexBloombergMunicipalBondIndex18673BroadBasedIndexMember" priority="1"/><link:label xlink:type="resource" xlink:label="label_DWSIndexBloombergMunicipalBondIndex18673BroadBasedIndexMember_18673" xlink:role="http://www.xbrl.org/2003/role/label" xml:lang="en-US">DWS Index: Bloomberg Municipal Bond Index_18673</link:label><link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="DWSIndexBloombergMunicipalBondIndex18673BroadBasedIndexMember" xlink:to="label_DWSIndexBloombergMunicipalBondIndex18673BroadBasedIndexMember_18673" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_DWSIndexBloombergMunicipalBondIndex18674BroadBasedIndexMember" xlink:label="DWSIndexBloombergMunicipalBondIndex18674BroadBasedIndexMember"/><link:label xlink:type="resource" xlink:label="label_DWSIndexBloombergMunicipalBondIndex18674BroadBasedIndexMember" xlink:role="http://www.xbrl.org/2003/role/terseLabel" xml:lang="en-US">DWS Index: Bloomberg Municipal Bond Index</link:label><link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="DWSIndexBloombergMunicipalBondIndex18674BroadBasedIndexMember" xlink:to="label_DWSIndexBloombergMunicipalBondIndex18674BroadBasedIndexMember" priority="1"/><link:label xlink:type="resource" xlink:label="label_DWSIndexBloombergMunicipalBondIndex18674BroadBasedIndexMember_18674" xlink:role="http://www.xbrl.org/2003/role/label" xml:lang="en-US">DWS Index: Bloomberg Municipal Bond Index_18674</link:label><link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="DWSIndexBloombergMunicipalBondIndex18674BroadBasedIndexMember" xlink:to="label_DWSIndexBloombergMunicipalBondIndex18674BroadBasedIndexMember_18674" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_DWSIndexBloombergMunicipalBondIndex18676BroadBasedIndexMember" xlink:label="DWSIndexBloombergMunicipalBondIndex18676BroadBasedIndexMember"/><link:label xlink:type="resource" xlink:label="label_DWSIndexBloombergMunicipalBondIndex18676BroadBasedIndexMember" xlink:role="http://www.xbrl.org/2003/role/terseLabel" xml:lang="en-US">DWS Index: Bloomberg Municipal Bond Index</link:label><link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="DWSIndexBloombergMunicipalBondIndex18676BroadBasedIndexMember" xlink:to="label_DWSIndexBloombergMunicipalBondIndex18676BroadBasedIndexMember" priority="1"/><link:label xlink:type="resource" xlink:label="label_DWSIndexBloombergMunicipalBondIndex18676BroadBasedIndexMember_18676" xlink:role="http://www.xbrl.org/2003/role/label" xml:lang="en-US">DWS Index: Bloomberg Municipal Bond Index_18676</link:label><link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="DWSIndexBloombergMunicipalBondIndex18676BroadBasedIndexMember" xlink:to="label_DWSIndexBloombergMunicipalBondIndex18676BroadBasedIndexMember_18676" priority="1"/><link:loc xlink:type="locator" xlink:href="https://xbrl.fasb.org/us-gaap/2025/elts/us-gaap-2025.xsd#us-gaap_InvestmentTypeAxis" xlink:label="InvestmentTypeAxis"/><link:label xlink:type="resource" xlink:label="label_InvestmentTypeAxis" xlink:role="http://www.xbrl.org/2003/role/label" xml:lang="en-US">Investment Type [Axis]</link:label><link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="InvestmentTypeAxis" xlink:to="label_InvestmentTypeAxis" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_RevenueBondsCTIMember" xlink:label="RevenueBondsCTIMember"/><link:label xlink:type="resource" xlink:label="label_RevenueBondsCTIMember" xlink:role="http://www.xbrl.org/2003/role/label" xml:lang="en-US">Revenue Bonds</link:label><link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="RevenueBondsCTIMember" xlink:to="label_RevenueBondsCTIMember" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_GeneralObligationBondsCTIMember" xlink:label="GeneralObligationBondsCTIMember"/><link:label xlink:type="resource" xlink:label="label_GeneralObligationBondsCTIMember" xlink:role="http://www.xbrl.org/2003/role/label" xml:lang="en-US">General Obligation Bonds</link:label><link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="GeneralObligationBondsCTIMember" xlink:to="label_GeneralObligationBondsCTIMember" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_LeaseObligationsCTIMember" xlink:label="LeaseObligationsCTIMember"/><link:label xlink:type="resource" xlink:label="label_LeaseObligationsCTIMember" xlink:role="http://www.xbrl.org/2003/role/label" xml:lang="en-US">Lease Obligations</link:label><link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="LeaseObligationsCTIMember" xlink:to="label_LeaseObligationsCTIMember" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_VariableRateDemandNotesCTIMember" xlink:label="VariableRateDemandNotesCTIMember"/><link:label xlink:type="resource" xlink:label="label_VariableRateDemandNotesCTIMember" xlink:role="http://www.xbrl.org/2003/role/label" xml:lang="en-US">Variable Rate Demand Notes</link:label><link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="VariableRateDemandNotesCTIMember" xlink:to="label_VariableRateDemandNotesCTIMember" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_EscrowtoMaturityPrerefundedBondsCTIMember" xlink:label="EscrowtoMaturityPrerefundedBondsCTIMember"/><link:label xlink:type="resource" xlink:label="label_EscrowtoMaturityPrerefundedBondsCTIMember" xlink:role="http://www.xbrl.org/2003/role/label" xml:lang="en-US">Escrow to Maturity/Prerefunded Bonds</link:label><link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="EscrowtoMaturityPrerefundedBondsCTIMember" xlink:to="label_EscrowtoMaturityPrerefundedBondsCTIMember" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_OtherCTIMember" xlink:label="OtherCTIMember"/><link:label xlink:type="resource" xlink:label="label_OtherCTIMember" xlink:role="http://www.xbrl.org/2003/role/label" xml:lang="en-US">Other</link:label><link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="OtherCTIMember" xlink:to="label_OtherCTIMember" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_OtherAssetsandLiabilitiesNetCTIMember" xlink:label="OtherAssetsandLiabilitiesNetCTIMember"/><link:label xlink:type="resource" xlink:label="label_OtherAssetsandLiabilitiesNetCTIMember" xlink:role="http://www.xbrl.org/2003/role/label" xml:lang="en-US">Other Assets and Liabilities, Net</link:label><link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="OtherAssetsandLiabilitiesNetCTIMember" xlink:to="label_OtherAssetsandLiabilitiesNetCTIMember" priority="1"/><link:loc xlink:type="locator" xlink:href="https://xbrl.fasb.org/srt/2025/elts/srt-2025.xsd#srt_StandardPoorsAAARatingMember" xlink:label="StandardPoorsAAARatingMember"/><link:label xlink:type="resource" xlink:label="label_StandardPoorsAAARatingMember" xlink:role="http://www.xbrl.org/2003/role/label" xml:lang="en-US">AAA</link:label><link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="StandardPoorsAAARatingMember" xlink:to="label_StandardPoorsAAARatingMember" priority="1"/><link:loc xlink:type="locator" xlink:href="https://xbrl.fasb.org/srt/2025/elts/srt-2025.xsd#srt_StandardPoorsAARatingMember" xlink:label="StandardPoorsAARatingMember"/><link:label xlink:type="resource" xlink:label="label_StandardPoorsAARatingMember" xlink:role="http://www.xbrl.org/2003/role/label" xml:lang="en-US">AA</link:label><link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="StandardPoorsAARatingMember" xlink:to="label_StandardPoorsAARatingMember" priority="1"/><link:loc xlink:type="locator" xlink:href="https://xbrl.fasb.org/srt/2025/elts/srt-2025.xsd#srt_StandardPoorsARatingMember" xlink:label="StandardPoorsARatingMember"/><link:label xlink:type="resource" xlink:label="label_StandardPoorsARatingMember" xlink:role="http://www.xbrl.org/2003/role/label" xml:lang="en-US">A</link:label><link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="StandardPoorsARatingMember" xlink:to="label_StandardPoorsARatingMember" priority="1"/><link:loc xlink:type="locator" xlink:href="https://xbrl.fasb.org/srt/2025/elts/srt-2025.xsd#srt_StandardPoorsBBBRatingMember" xlink:label="StandardPoorsBBBRatingMember"/><link:label xlink:type="resource" xlink:label="label_StandardPoorsBBBRatingMember" xlink:role="http://www.xbrl.org/2003/role/label" xml:lang="en-US">BBB</link:label><link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="StandardPoorsBBBRatingMember" xlink:to="label_StandardPoorsBBBRatingMember" priority="1"/><link:loc xlink:type="locator" xlink:href="https://xbrl.fasb.org/srt/2025/elts/srt-2025.xsd#srt_StandardPoorsBBRatingMember" xlink:label="StandardPoorsBBRatingMember"/><link:label xlink:type="resource" xlink:label="label_StandardPoorsBBRatingMember" xlink:role="http://www.xbrl.org/2003/role/label" xml:lang="en-US">BB</link:label><link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="StandardPoorsBBRatingMember" xlink:to="label_StandardPoorsBBRatingMember" priority="1"/><link:loc xlink:type="locator" xlink:href="https://xbrl.fasb.org/srt/2025/elts/srt-2025.xsd#srt_StandardPoorsBRatingMember" xlink:label="StandardPoorsBRatingMember"/><link:label xlink:type="resource" xlink:label="label_StandardPoorsBRatingMember" xlink:role="http://www.xbrl.org/2003/role/label" xml:lang="en-US">B</link:label><link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="StandardPoorsBRatingMember" xlink:to="label_StandardPoorsBRatingMember" priority="1"/><link:loc xlink:type="locator" xlink:href="https://xbrl.fasb.org/srt/2025/elts/srt-2025.xsd#srt_StandardPoorsCCCRatingMember" xlink:label="StandardPoorsCCCRatingMember"/><link:label xlink:type="resource" xlink:label="label_StandardPoorsCCCRatingMember" xlink:role="http://www.xbrl.org/2003/role/label" xml:lang="en-US">CCC</link:label><link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="StandardPoorsCCCRatingMember" xlink:to="label_StandardPoorsCCCRatingMember" priority="1"/><link:loc xlink:type="locator" xlink:href="https://xbrl.fasb.org/srt/2025/elts/srt-2025.xsd#srt_StandardPoorsCCRatingMember" xlink:label="StandardPoorsCCRatingMember"/><link:label xlink:type="resource" xlink:label="label_StandardPoorsCCRatingMember" xlink:role="http://www.xbrl.org/2003/role/label" xml:lang="en-US">CC</link:label><link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="StandardPoorsCCRatingMember" xlink:to="label_StandardPoorsCCRatingMember" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_NRCTIMember" xlink:label="NRCTIMember"/><link:label xlink:type="resource" xlink:label="label_NRCTIMember" xlink:role="http://www.xbrl.org/2003/role/label" xml:lang="en-US">NR</link:label><link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="NRCTIMember" xlink:to="label_NRCTIMember" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_TexasCTIMember" xlink:label="TexasCTIMember"/><link:label xlink:type="resource" xlink:label="label_TexasCTIMember" xlink:role="http://www.xbrl.org/2003/role/label" xml:lang="en-US">Texas</link:label><link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="TexasCTIMember" xlink:to="label_TexasCTIMember" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_NewYorkCTIMember" xlink:label="NewYorkCTIMember"/><link:label xlink:type="resource" xlink:label="label_NewYorkCTIMember" xlink:role="http://www.xbrl.org/2003/role/label" xml:lang="en-US">New York</link:label><link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="NewYorkCTIMember" xlink:to="label_NewYorkCTIMember" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_FloridaCTIMember" xlink:label="FloridaCTIMember"/><link:label xlink:type="resource" xlink:label="label_FloridaCTIMember" xlink:role="http://www.xbrl.org/2003/role/label" xml:lang="en-US">Florida</link:label><link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="FloridaCTIMember" xlink:to="label_FloridaCTIMember" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_IllinoisCTIMember" xlink:label="IllinoisCTIMember"/><link:label xlink:type="resource" xlink:label="label_IllinoisCTIMember" xlink:role="http://www.xbrl.org/2003/role/label" xml:lang="en-US">Illinois</link:label><link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="IllinoisCTIMember" xlink:to="label_IllinoisCTIMember" priority="1"/><link:loc xlink:type="locator" xlink:href="#dws_WisconsinCTIMember" xlink:label="WisconsinCTIMember"/><link:label xlink:type="resource" xlink:label="label_WisconsinCTIMember" xlink:role="http://www.xbrl.org/2003/role/label" xml:lang="en-US">Wisconsin</link:label><link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="WisconsinCTIMember" xlink:to="label_WisconsinCTIMember" priority="1"/><link:loc xlink:type="locator" xlink:href="https://xbrl.sec.gov/dei/2025/dei-2025.xsd#dei_NoTradingSymbolFlag" xlink:label="NoTradingSymbolFlag"/><link:label xlink:type="resource" xlink:label="label_NoTradingSymbolFlag" xlink:role="http://www.xbrl.org/2003/role/label" xml:lang="en-US">No Trading Symbol [Flag]</link:label><link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="NoTradingSymbolFlag" xlink:to="label_NoTradingSymbolFlag" priority="1"/><link:loc xlink:type="locator" xlink:href="https://xbrl.fasb.org/us-gaap/2025/elts/us-gaap-2025.xsd#us-gaap_AssetsNet" xlink:label="AssetsNet"/><link:label xlink:type="resource" xlink:label="label_AssetsNet" xlink:role="http://www.xbrl.org/2003/role/label" xml:lang="en-US">AssetsNet</link:label><link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="AssetsNet" xlink:to="label_AssetsNet" priority="1"/><link:loc xlink:type="locator" xlink:href="https://xbrl.fasb.org/us-gaap/2025/elts/us-gaap-2025.xsd#us-gaap_InvestmentCompanyPortfolioTurnover" xlink:label="InvestmentCompanyPortfolioTurnover"/><link:label xlink:type="resource" xlink:label="label_InvestmentCompanyPortfolioTurnover" xlink:role="http://www.xbrl.org/2003/role/label" xml:lang="en-US">InvestmentCompanyPortfolioTurnover</link:label><link:labelArc xlink:type="arc" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="InvestmentCompanyPortfolioTurnover" xlink:to="label_InvestmentCompanyPortfolioTurnover" priority="1"/></link:labelLink></link:linkbase></appinfo></annotation><element name="C000016740Member" id="dws_C000016740Member" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" abstract="true" nillable="true" xbrli:periodType="duration"/><element name="C000016743Member" id="dws_C000016743Member" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" abstract="true" nillable="true" xbrli:periodType="duration"/><element name="C000016744Member" id="dws_C000016744Member" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" abstract="true" nillable="true" xbrli:periodType="duration"/><element name="C000016745Member" id="dws_C000016745Member" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" abstract="true" nillable="true" xbrli:periodType="duration"/><element name="DWSIndexBloombergMunicipalBondIndex18675BroadBasedIndexMember" id="dws_DWSIndexBloombergMunicipalBondIndex18675BroadBasedIndexMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" abstract="true" nillable="true" xbrli:periodType="duration"/><element name="DWSIndexBloombergMunicipalBondIndex18673BroadBasedIndexMember" id="dws_DWSIndexBloombergMunicipalBondIndex18673BroadBasedIndexMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" abstract="true" nillable="true" xbrli:periodType="duration"/><element name="DWSIndexBloombergMunicipalBondIndex18674BroadBasedIndexMember" id="dws_DWSIndexBloombergMunicipalBondIndex18674BroadBasedIndexMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" abstract="true" nillable="true" xbrli:periodType="duration"/><element name="DWSIndexBloombergMunicipalBondIndex18676BroadBasedIndexMember" id="dws_DWSIndexBloombergMunicipalBondIndex18676BroadBasedIndexMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" abstract="true" nillable="true" xbrli:periodType="duration"/><element name="RevenueBondsCTIMember" id="dws_RevenueBondsCTIMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" abstract="true" nillable="true" xbrli:periodType="duration"/><element name="GeneralObligationBondsCTIMember" id="dws_GeneralObligationBondsCTIMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" abstract="true" nillable="true" xbrli:periodType="duration"/><element name="LeaseObligationsCTIMember" id="dws_LeaseObligationsCTIMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" abstract="true" nillable="true" xbrli:periodType="duration"/><element name="VariableRateDemandNotesCTIMember" id="dws_VariableRateDemandNotesCTIMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" abstract="true" nillable="true" xbrli:periodType="duration"/><element name="EscrowtoMaturityPrerefundedBondsCTIMember" id="dws_EscrowtoMaturityPrerefundedBondsCTIMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" abstract="true" nillable="true" xbrli:periodType="duration"/><element name="OtherCTIMember" id="dws_OtherCTIMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" abstract="true" nillable="true" xbrli:periodType="duration"/><element name="OtherAssetsandLiabilitiesNetCTIMember" id="dws_OtherAssetsandLiabilitiesNetCTIMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" abstract="true" nillable="true" xbrli:periodType="duration"/><element name="NRCTIMember" id="dws_NRCTIMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" abstract="true" nillable="true" xbrli:periodType="duration"/><element name="TexasCTIMember" id="dws_TexasCTIMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" abstract="true" nillable="true" xbrli:periodType="duration"/><element name="NewYorkCTIMember" id="dws_NewYorkCTIMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" abstract="true" nillable="true" xbrli:periodType="duration"/><element name="FloridaCTIMember" id="dws_FloridaCTIMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" abstract="true" nillable="true" xbrli:periodType="duration"/><element name="IllinoisCTIMember" id="dws_IllinoisCTIMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" abstract="true" nillable="true" xbrli:periodType="duration"/><element name="WisconsinCTIMember" id="dws_WisconsinCTIMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" abstract="true" nillable="true" xbrli:periodType="duration"/></schema>
