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        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
    </xs:appinfo>
  </xs:annotation>
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  <xs:element id="rio_NetOperatingExpenses" abstract="false" name="NetOperatingExpenses" nillable="true" xbrli:periodType="duration" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="rio_ProfitBeforeFinanceItemsAndTaxation" abstract="false" name="ProfitBeforeFinanceItemsAndTaxation" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="rio_FinanceItemsAbstract" abstract="true" name="FinanceItemsAbstract" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="xbrli:stringItemType"/>
  <xs:element id="rio_ExchangeGainsLossesOnUsDollarExternalDebtAndIntraGroup" abstract="false" name="ExchangeGainsLossesOnUsDollarExternalDebtAndIntraGroup" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="rio_ExpenseDueToUndwindingOfDiscountOnProvisionsAndReceivables" abstract="false" name="ExpenseDueToUndwindingOfDiscountOnProvisionsAndReceivables" nillable="true" xbrli:periodType="duration" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="rio_ChangeInFairValueOfEquityInvestmentsAtFairValueThroughOtherComprehensiveIncome" abstract="false" name="ChangeInFairValueOfEquityInvestmentsAtFairValueThroughOtherComprehensiveIncome" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
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  <xs:element id="rio_CurrencyTranslationGainChargeArisingOnDualListedCompaniesShareCapital" abstract="false" name="CurrencyTranslationGainChargeArisingOnDualListedCompaniesShareCapital" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="rio_CashFlowsFromUsedInConsolidatedOperations" abstract="false" name="CashFlowsFromUsedInConsolidatedOperations" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="rio_CashFlowBeforeFinancingActivities" abstract="false" name="CashFlowBeforeFinancingActivities" nillable="true" xbrli:periodType="duration" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="rio_UtilisationOfProvisionsForOtherProvisionsIncludingOnerousContractsAndLegalDisputes" abstract="false" name="UtilisationOfProvisionsForOtherProvisionsIncludingOnerousContractsAndLegalDisputes" nillable="true" xbrli:periodType="duration" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
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  <xs:element id="rio_BridgeLoanFacilityMember" abstract="true" name="BridgeLoanFacilityMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types1:domainItemType"/>
  <xs:element id="rio_FixedAndFloatingRateSECRegisteredDebtSecuritiesMember" abstract="true" name="FixedAndFloatingRateSECRegisteredDebtSecuritiesMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types1:domainItemType"/>
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  <xs:element id="rio_ChalcoIronOreHoldingsLtdCIOHMember" abstract="true" name="ChalcoIronOreHoldingsLtdCIOHMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types1:domainItemType"/>
  <xs:element id="rio_TotalNetOutflowsInIronOreProject" abstract="false" name="TotalNetOutflowsInIronOreProject" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="rio_StatementsTable" abstract="true" name="StatementsTable" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrldt:hypercubeItem" type="xbrli:stringItemType"/>
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  <xs:element id="rio_StatementsLineItems" abstract="true" name="StatementsLineItems" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="xbrli:stringItemType"/>
  <xs:element id="rio_CurrentProvisionsForEmployeeBenefitsAndOtherEmploymentCosts" abstract="false" name="CurrentProvisionsForEmployeeBenefitsAndOtherEmploymentCosts" nillable="true" xbrli:periodType="instant" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
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  <xs:element id="rio_DividendsProposedOrDeclaredBeforeFinancialStatementsAuthorisedForIssueButNotRecognisedAsDistributionToOwnersPerShareOrdinarySharesPerShare" abstract="false" name="DividendsProposedOrDeclaredBeforeFinancialStatementsAuthorisedForIssueButNotRecognisedAsDistributionToOwnersPerShareOrdinarySharesPerShare" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types1:perShareItemType"/>
  <xs:element id="rio_BasisOfPresentationAbstract" abstract="true" name="BasisOfPresentationAbstract" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="xbrli:stringItemType"/>
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  <xs:element id="rio_ShareOfEquityAccountedUnitsAndAdjustmentsMember" abstract="true" name="ShareOfEquityAccountedUnitsAndAdjustmentsMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types1:domainItemType"/>
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  <xs:element id="rio_ExplorationAndEvaluationNotAttributedToProductGroupsMember" abstract="true" name="ExplorationAndEvaluationNotAttributedToProductGroupsMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types1:domainItemType"/>
  <xs:element id="rio_GrossProductSalesMember" abstract="true" name="GrossProductSalesMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types1:domainItemType"/>
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  <xs:element id="rio_ShareOfEquityAccountedRevenueDeductedToReconcileToRevenuePerIncomeStatement" abstract="false" name="ShareOfEquityAccountedRevenueDeductedToReconcileToRevenuePerIncomeStatement" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="rio_ShareOfSalesRevenueOfEquityAccountedUnits" abstract="false" name="ShareOfSalesRevenueOfEquityAccountedUnits" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
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  <xs:element id="rio_DepreciationAndAmortisationRecognisedInProfitOrLossExcludingCapitalisedDepreciation" abstract="false" name="DepreciationAndAmortisationRecognisedInProfitOrLossExcludingCapitalisedDepreciation" nillable="true" xbrli:periodType="duration" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
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  <xs:element id="rio_GainsLossesOnChangeInFairValueOfCommodityDerivatives" abstract="false" name="GainsLossesOnChangeInFairValueOfCommodityDerivatives" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
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  <xs:element id="rio_ShareOfProfitLossOfAssociatesAndJointVenturesAccountedForUsingEquityMethodNet" abstract="false" name="ShareOfProfitLossOfAssociatesAndJointVenturesAccountedForUsingEquityMethodNet" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="rio_GreaterChinaMember" abstract="true" name="GreaterChinaMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types1:domainItemType"/>
  <xs:element id="rio_AsiaExcludingGreaterChinaAndJapanMember" abstract="true" name="AsiaExcludingGreaterChinaAndJapanMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types1:domainItemType"/>
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  <xs:element id="rio_OtherProductsAndFreightServicesMember" abstract="true" name="OtherProductsAndFreightServicesMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types1:domainItemType"/>
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  <xs:element id="rio_ShareOfProfitLossAfterTaxInEAUsMember" abstract="true" name="ShareOfProfitLossAfterTaxInEAUsMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types1:domainItemType"/>
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  <xs:element id="rio_ImpairmentLossReversalOfImpairmentLossRecognisedInProfitOrLossTaxation" abstract="false" name="ImpairmentLossReversalOfImpairmentLossRecognisedInProfitOrLossTaxation" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
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  <xs:element id="rio_TaxEffectOfOtherTaxRatesApplicableUkAndAustraliaOnUnderlyingEarnings" abstract="false" name="TaxEffectOfOtherTaxRatesApplicableUkAndAustraliaOnUnderlyingEarnings" nillable="true" xbrli:periodType="duration" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
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  <xs:element id="rio_ArcadiumLithiumPlcMember" abstract="true" name="ArcadiumLithiumPlcMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types1:domainItemType"/>
  <xs:element id="rio_SumitomoMetalMiningCoSMMMember" abstract="true" name="SumitomoMetalMiningCoSMMMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types1:domainItemType"/>
  <xs:element id="rio_AcquisitionPurchasePricePerShare" abstract="false" name="AcquisitionPurchasePricePerShare" nillable="true" xbrli:periodType="instant" substitutionGroup="xbrli:item" type="dtr-types:perShareItemType"/>
  <xs:element id="rio_ConsiderationPaidOfEquityToShareholders" abstract="false" name="ConsiderationPaidOfEquityToShareholders" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="rio_IncreaseDecreaseOnConvertibleLoanNotesSettledOnChangeOfControlAsOfAcquisitionDate" abstract="false" name="IncreaseDecreaseOnConvertibleLoanNotesSettledOnChangeOfControlAsOfAcquisitionDate" nillable="true" xbrli:periodType="duration" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="rio_IncreaseDecreaseInNetDebt" abstract="false" name="IncreaseDecreaseInNetDebt" nillable="true" xbrli:periodType="duration" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="rio_IncreaseDecreaseInNetDebtOnAcquisitionDate" abstract="false" name="IncreaseDecreaseInNetDebtOnAcquisitionDate" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="rio_IncreaseDecreaseInNetDebtDueToAdvancementPriorToAcquisition" abstract="false" name="IncreaseDecreaseInNetDebtDueToAdvancementPriorToAcquisition" nillable="true" xbrli:periodType="duration" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="rio_JointVenturePercentageOfShareOfAssetsAndLiabilities" abstract="false" name="JointVenturePercentageOfShareOfAssetsAndLiabilities" nillable="true" xbrli:periodType="instant" substitutionGroup="xbrli:item" type="dtr-types:percentItemType"/>
  <xs:element id="rio_ProceedsFromDivestmentInJointVentureProject" abstract="false" name="ProceedsFromDivestmentInJointVentureProject" nillable="true" xbrli:periodType="duration" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="rio_GainLossOnDivestmentInJointVentureProject" abstract="false" name="GainLossOnDivestmentInJointVentureProject" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="rio_JointVentureDeferredContingentConsiderationOnFutureMilestones" abstract="false" name="JointVentureDeferredContingentConsiderationOnFutureMilestones" nillable="true" xbrli:periodType="instant" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="rio_OlarozLithiumCarbonateMineMember" abstract="true" name="OlarozLithiumCarbonateMineMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types1:domainItemType"/>
  <xs:element id="rio_NemaskaLithiumDevelopmentProjectMember" abstract="true" name="NemaskaLithiumDevelopmentProjectMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types1:domainItemType"/>
  <xs:element id="rio_CloseDownRestorationAndEnvironmentProvisionsRecognisedAsOfAcquisitionDate" abstract="false" name="CloseDownRestorationAndEnvironmentProvisionsRecognisedAsOfAcquisitionDate" nillable="true" xbrli:periodType="instant" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="rio_OtherProvisionsRecognisedAsOfAcquisitionDate" abstract="false" name="OtherProvisionsRecognisedAsOfAcquisitionDate" nillable="true" xbrli:periodType="instant" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="rio_OtherAssetsAndLiabilitiesRecognisedAsOfAcquisitionDate" abstract="false" name="OtherAssetsAndLiabilitiesRecognisedAsOfAcquisitionDate" nillable="true" xbrli:periodType="instant" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="rio_IdentifiableAssetsAcquiredLiabilitiesAssumedExcludingGoodwillAndNoncontrollingInterest" abstract="false" name="IdentifiableAssetsAcquiredLiabilitiesAssumedExcludingGoodwillAndNoncontrollingInterest" nillable="true" xbrli:periodType="instant" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="rio_PaymentOfLoanOrigination" abstract="false" name="PaymentOfLoanOrigination" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="rio_IncreaseDecreaseOnBorrowingsAsOfAcquisitionDate" abstract="false" name="IncreaseDecreaseOnBorrowingsAsOfAcquisitionDate" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="rio_AdjustmentsForIncreaseDecreaseInDebtInstrumentsAcquired" abstract="false" name="AdjustmentsForIncreaseDecreaseInDebtInstrumentsAcquired" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="rio_ConsiderationPaidForSettlementOfConvertibleLoanNotes" abstract="false" name="ConsiderationPaidForSettlementOfConvertibleLoanNotes" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="rio_AdjustmentOnCurrencyTranslation" abstract="false" name="AdjustmentOnCurrencyTranslation" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="rio_AdjustmentsToPropertyPlantAndEquipmentAbstract" abstract="true" name="AdjustmentsToPropertyPlantAndEquipmentAbstract" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="xbrli:stringItemType"/>
  <xs:element id="rio_IncreaseInNewAndExistingProvisionsMiningPropertiesAndRightOfUseAssets" abstract="false" name="IncreaseInNewAndExistingProvisionsMiningPropertiesAndRightOfUseAssets" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="rio_ChargedCreditedToProfitAbstract" abstract="true" name="ChargedCreditedToProfitAbstract" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="xbrli:stringItemType"/>
  <xs:element id="rio_IncreaseInNewAndExistingProvisions" abstract="false" name="IncreaseInNewAndExistingProvisions" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="rio_BalanceSheetAnalysisAbstract" abstract="true" name="BalanceSheetAnalysisAbstract" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="xbrli:stringItemType"/>
  <xs:element id="rio_ClosureRelatedReceivables" abstract="false" name="ClosureRelatedReceivables" nillable="true" xbrli:periodType="instant" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="rio_NotHeldAtFairValueMember" abstract="true" name="NotHeldAtFairValueMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types1:domainItemType"/>
  <xs:element id="rio_EquitySharesAndQuotedFunds" abstract="false" name="EquitySharesAndQuotedFunds" nillable="true" xbrli:periodType="instant" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="rio_OtherInvestmentsIncludingLoans" abstract="false" name="OtherInvestmentsIncludingLoans" nillable="true" xbrli:periodType="instant" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="rio_TradeAndOtherFinancialReceivables" abstract="false" name="TradeAndOtherFinancialReceivables" nillable="true" xbrli:periodType="instant" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="rio_LoansToEquityAccountedUnits" abstract="false" name="LoansToEquityAccountedUnits" nillable="true" xbrli:periodType="instant" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="rio_DerivativeFinancialAssetsRelatedToNetDebtAtFairValue" abstract="false" name="DerivativeFinancialAssetsRelatedToNetDebtAtFairValue" nillable="true" xbrli:periodType="instant" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="rio_TradeAndOtherFinancialPayables" abstract="false" name="TradeAndOtherFinancialPayables" nillable="true" xbrli:periodType="instant" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="rio_DerivativeFinancialLiabilitiesRelatedToNetDebtAtFairValue" abstract="false" name="DerivativeFinancialLiabilitiesRelatedToNetDebtAtFairValue" nillable="true" xbrli:periodType="instant" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="rio_RoyaltyReceivablesMember" abstract="true" name="RoyaltyReceivablesMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types1:domainItemType"/>
  <xs:element id="rio_ProvisionallyPricedReceivablesMember" abstract="true" name="ProvisionallyPricedReceivablesMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types1:domainItemType"/>
  <xs:element id="rio_ForwardCommodityPriceAndMineProductionMeasurementInputMember" abstract="true" name="ForwardCommodityPriceAndMineProductionMeasurementInputMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types1:domainItemType"/>
  <xs:element id="rio_ApplicableForwardQuotedMetalPricesMeasurementInputMember" abstract="true" name="ApplicableForwardQuotedMetalPricesMeasurementInputMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types1:domainItemType"/>
  <xs:element id="rio_CloselyRelatedListedProductMember" abstract="true" name="CloselyRelatedListedProductMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types1:domainItemType"/>
  <xs:element id="rio_FinancialAssetsAndFinancialLiabilitiesAtFairValue" abstract="false" name="FinancialAssetsAndFinancialLiabilitiesAtFairValue" nillable="true" xbrli:periodType="instant" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="rio_RealisedGainsLossesIncludedInNetOperatingCosts" abstract="false" name="RealisedGainsLossesIncludedInNetOperatingCosts" nillable="true" xbrli:periodType="duration" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="rio_UnrealisedGainsIncludedInNetOperatingCosts" abstract="false" name="UnrealisedGainsIncludedInNetOperatingCosts" nillable="true" xbrli:periodType="duration" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="rio_UnrealisedGainOrLossTransferredIntoOtherComprehensiveIncome" abstract="false" name="UnrealisedGainOrLossTransferredIntoOtherComprehensiveIncome" nillable="true" xbrli:periodType="duration" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="rio_PurchasesFairValueMeasurementsAssetsAndLiabilities" abstract="false" name="PurchasesFairValueMeasurementsAssetsAndLiabilities" nillable="true" xbrli:periodType="duration" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="rio_DisposalOrMaturityOfFinancialInstruments" abstract="false" name="DisposalOrMaturityOfFinancialInstruments" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="rio_GainsLossesRecognisedInProfitOrLossForAssetsAndLiabilitiesHeld" abstract="false" name="GainsLossesRecognisedInProfitOrLossForAssetsAndLiabilitiesHeld" nillable="true" xbrli:periodType="duration" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="rio_ForwardElectricityPriceAndEnergyVolumeMember" abstract="true" name="ForwardElectricityPriceAndEnergyVolumeMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types1:domainItemType"/>
  <xs:element id="rio_LMEForwardAluminumPriceAndMidwestPremiumAndBilletPremiumMeasurementInputMember" abstract="true" name="LMEForwardAluminumPriceAndMidwestPremiumAndBilletPremiumMeasurementInputMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types1:domainItemType"/>
  <xs:element id="rio_RenewablePowerPurchaseAgreementsMember" abstract="true" name="RenewablePowerPurchaseAgreementsMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types1:domainItemType"/>
  <xs:element id="rio_DerivativesEmbeddedInElectricityContractsMember" abstract="true" name="DerivativesEmbeddedInElectricityContractsMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types1:domainItemType"/>
  <xs:element id="rio_PercentageChangeInForecastElectricityPrices" abstract="false" name="PercentageChangeInForecastElectricityPrices" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types1:percentItemType"/>
  <xs:element id="rio_IncreaseInCarryingValueOfRenewablePowerPurchaseAgreementsDueToForecastElectricityPrices" abstract="false" name="IncreaseInCarryingValueOfRenewablePowerPurchaseAgreementsDueToForecastElectricityPrices" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="rio_DecreaseInCarryingValueOfRenewablePowerPurchaseAgreementsDueToForecastElectricityPrices" abstract="false" name="DecreaseInCarryingValueOfRenewablePowerPurchaseAgreementsDueToForecastElectricityPrices" nillable="true" xbrli:periodType="duration" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="rio_DebtInstrumentsRestrictiveCovenants" abstract="false" name="DebtInstrumentsRestrictiveCovenants" nillable="true" xbrli:periodType="instant" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="rio_ListedBondsMember" abstract="true" name="ListedBondsMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types1:domainItemType"/>
  <xs:element id="rio_OyuTolgoiProjectFinanceMember" abstract="true" name="OyuTolgoiProjectFinanceMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types1:domainItemType"/>
  <xs:element id="rio_OtherBorrowingsMember" abstract="true" name="OtherBorrowingsMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types1:domainItemType"/>
  <xs:element id="rio_ThreeYearNoteFloatingRateMember" abstract="true" name="ThreeYearNoteFloatingRateMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types1:domainItemType"/>
  <xs:element id="rio_FixedCouponMember" abstract="true" name="FixedCouponMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types1:domainItemType"/>
  <xs:element id="rio_BorrowingsFairValue" abstract="false" name="BorrowingsFairValue" nillable="true" xbrli:periodType="instant" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="rio_BorrowingsNumberOfTranches" abstract="false" name="BorrowingsNumberOfTranches" nillable="true" xbrli:periodType="instant" substitutionGroup="xbrli:item" type="xbrli:integerItemType"/>
  <xs:element id="rio_BorrowingsDebtInstrumentTerm" abstract="false" name="BorrowingsDebtInstrumentTerm" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="xbrli:durationItemType"/>
  <xs:element id="rio_NumberOfInternationalLenders" abstract="false" name="NumberOfInternationalLenders" nillable="true" xbrli:periodType="instant" substitutionGroup="xbrli:item" type="xbrli:integerItemType"/>
  <xs:element id="rio_BorrowingsBasisSpreadOnVariableRate" abstract="false" name="BorrowingsBasisSpreadOnVariableRate" nillable="true" xbrli:periodType="instant" substitutionGroup="xbrli:item" type="dtr-types:percentItemType"/>
  <xs:element id="rio_OtherDisclosuresTable" abstract="true" name="OtherDisclosuresTable" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrldt:hypercubeItem" type="xbrli:stringItemType"/>
  <xs:element id="rio_RioTintoFinanceUsaLimitedAndRioTintoFinanceUsaPlcMember" abstract="true" name="RioTintoFinanceUsaLimitedAndRioTintoFinanceUsaPlcMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types1:domainItemType"/>
  <xs:element id="rio_SimferJerseyLimitedMember" abstract="true" name="SimferJerseyLimitedMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types1:domainItemType"/>
  <xs:element id="rio_WinningConsortiumSimandouRailwayPteLtdAndWinningConsortiumSimandouPortsPteLtdMember" abstract="true" name="WinningConsortiumSimandouRailwayPteLtdAndWinningConsortiumSimandouPortsPteLtdMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types1:domainItemType"/>
  <xs:element id="rio_OtherDisclosuresLineItems" abstract="true" name="OtherDisclosuresLineItems" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="xbrli:stringItemType"/>
  <xs:element id="rio_ContractualPayments" abstract="false" name="ContractualPayments" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
</xs:schema>
