<?xml version="1.0" encoding="UTF-8"?>

<!--XBRL Document Created with the Workiva Platform-->
<!--Copyright 2026 Workiva-->
<!--r:019f5d1b-9919-73e4-8e46-99d6484158d0,g:f46fd56a-0a6e-4206-a2ce-104cbd2d841a-->
<link:linkbase xmlns:link="http://www.xbrl.org/2003/linkbase" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://www.xbrl.org/2003/linkbase http://www.xbrl.org/2003/xbrl-linkbase-2003-12-31.xsd">
  <link:roleRef roleURI="http://www.valero.com/role/DocumentandEntityInformation" xlink:type="simple" xlink:href="vlo-20260716.xsd#DocumentandEntityInformation"/>
  <link:presentationLink xlink:role="http://www.valero.com/role/DocumentandEntityInformation" xlink:type="extended">
    <link:loc xlink:type="locator" xlink:label="loc_dei_CoverAbstract_019f5d1b-9919-74c4-b96a-97307176dbf9" xlink:href="https://xbrl.sec.gov/dei/2025/dei-2025.xsd#dei_CoverAbstract"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_DocumentType_019f5d1b-9919-703b-966e-c7f2d23af9e7" xlink:href="https://xbrl.sec.gov/dei/2025/dei-2025.xsd#dei_DocumentType"/>
    <link:presentationArc order="1" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_019f5d1b-9919-74c4-b96a-97307176dbf9" xlink:to="loc_dei_DocumentType_019f5d1b-9919-703b-966e-c7f2d23af9e7" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_DocumentPeriodEndDate_019f5d1b-9919-75e3-a206-251056a68de0" xlink:href="https://xbrl.sec.gov/dei/2025/dei-2025.xsd#dei_DocumentPeriodEndDate"/>
    <link:presentationArc order="2" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_019f5d1b-9919-74c4-b96a-97307176dbf9" xlink:to="loc_dei_DocumentPeriodEndDate_019f5d1b-9919-75e3-a206-251056a68de0" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_EntityRegistrantName_019f5d1b-9919-7b68-ba42-0b1438dbb56d" xlink:href="https://xbrl.sec.gov/dei/2025/dei-2025.xsd#dei_EntityRegistrantName"/>
    <link:presentationArc order="3" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_019f5d1b-9919-74c4-b96a-97307176dbf9" xlink:to="loc_dei_EntityRegistrantName_019f5d1b-9919-7b68-ba42-0b1438dbb56d" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_EntityIncorporationStateCountryCode_019f5d1b-9919-7432-9844-321b53299b6c" xlink:href="https://xbrl.sec.gov/dei/2025/dei-2025.xsd#dei_EntityIncorporationStateCountryCode"/>
    <link:presentationArc order="4" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_019f5d1b-9919-74c4-b96a-97307176dbf9" xlink:to="loc_dei_EntityIncorporationStateCountryCode_019f5d1b-9919-7432-9844-321b53299b6c" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_EntityFileNumber_019f5d1b-9919-7fb4-a706-cde5d7618d1c" xlink:href="https://xbrl.sec.gov/dei/2025/dei-2025.xsd#dei_EntityFileNumber"/>
    <link:presentationArc order="5" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_019f5d1b-9919-74c4-b96a-97307176dbf9" xlink:to="loc_dei_EntityFileNumber_019f5d1b-9919-7fb4-a706-cde5d7618d1c" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_EntityTaxIdentificationNumber_019f5d1b-9919-7ee0-9223-87e7b88d22f8" xlink:href="https://xbrl.sec.gov/dei/2025/dei-2025.xsd#dei_EntityTaxIdentificationNumber"/>
    <link:presentationArc order="6" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_019f5d1b-9919-74c4-b96a-97307176dbf9" xlink:to="loc_dei_EntityTaxIdentificationNumber_019f5d1b-9919-7ee0-9223-87e7b88d22f8" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_EntityAddressAddressLine1_019f5d1b-9919-770b-beb1-8ed54503e993" xlink:href="https://xbrl.sec.gov/dei/2025/dei-2025.xsd#dei_EntityAddressAddressLine1"/>
    <link:presentationArc order="7" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_019f5d1b-9919-74c4-b96a-97307176dbf9" xlink:to="loc_dei_EntityAddressAddressLine1_019f5d1b-9919-770b-beb1-8ed54503e993" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_EntityAddressCityOrTown_019f5d1b-9919-7214-a0b8-9cce24d93829" xlink:href="https://xbrl.sec.gov/dei/2025/dei-2025.xsd#dei_EntityAddressCityOrTown"/>
    <link:presentationArc order="8" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_019f5d1b-9919-74c4-b96a-97307176dbf9" xlink:to="loc_dei_EntityAddressCityOrTown_019f5d1b-9919-7214-a0b8-9cce24d93829" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_EntityAddressStateOrProvince_019f5d1b-9919-7d14-a968-9605c72d52be" xlink:href="https://xbrl.sec.gov/dei/2025/dei-2025.xsd#dei_EntityAddressStateOrProvince"/>
    <link:presentationArc order="9" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_019f5d1b-9919-74c4-b96a-97307176dbf9" xlink:to="loc_dei_EntityAddressStateOrProvince_019f5d1b-9919-7d14-a968-9605c72d52be" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_EntityAddressPostalZipCode_019f5d1b-9919-733e-9a56-48dd6dc6c06d" xlink:href="https://xbrl.sec.gov/dei/2025/dei-2025.xsd#dei_EntityAddressPostalZipCode"/>
    <link:presentationArc order="10" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_019f5d1b-9919-74c4-b96a-97307176dbf9" xlink:to="loc_dei_EntityAddressPostalZipCode_019f5d1b-9919-733e-9a56-48dd6dc6c06d" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_CityAreaCode_019f5d1b-9919-7cb0-bcf0-fd7ffaba1ae0" xlink:href="https://xbrl.sec.gov/dei/2025/dei-2025.xsd#dei_CityAreaCode"/>
    <link:presentationArc order="11" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_019f5d1b-9919-74c4-b96a-97307176dbf9" xlink:to="loc_dei_CityAreaCode_019f5d1b-9919-7cb0-bcf0-fd7ffaba1ae0" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_LocalPhoneNumber_019f5d1b-9919-7b50-9721-53bf4c3fdcd6" xlink:href="https://xbrl.sec.gov/dei/2025/dei-2025.xsd#dei_LocalPhoneNumber"/>
    <link:presentationArc order="12" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_019f5d1b-9919-74c4-b96a-97307176dbf9" xlink:to="loc_dei_LocalPhoneNumber_019f5d1b-9919-7b50-9721-53bf4c3fdcd6" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_WrittenCommunications_019f5d1b-9919-7f59-ac3b-8554f0d78227" xlink:href="https://xbrl.sec.gov/dei/2025/dei-2025.xsd#dei_WrittenCommunications"/>
    <link:presentationArc order="13" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_019f5d1b-9919-74c4-b96a-97307176dbf9" xlink:to="loc_dei_WrittenCommunications_019f5d1b-9919-7f59-ac3b-8554f0d78227" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_SolicitingMaterial_019f5d1b-9919-7033-affd-570c04482a76" xlink:href="https://xbrl.sec.gov/dei/2025/dei-2025.xsd#dei_SolicitingMaterial"/>
    <link:presentationArc order="14" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_019f5d1b-9919-74c4-b96a-97307176dbf9" xlink:to="loc_dei_SolicitingMaterial_019f5d1b-9919-7033-affd-570c04482a76" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_PreCommencementTenderOffer_019f5d1b-9919-72bf-a467-e67be475298c" xlink:href="https://xbrl.sec.gov/dei/2025/dei-2025.xsd#dei_PreCommencementTenderOffer"/>
    <link:presentationArc order="15" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_019f5d1b-9919-74c4-b96a-97307176dbf9" xlink:to="loc_dei_PreCommencementTenderOffer_019f5d1b-9919-72bf-a467-e67be475298c" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_PreCommencementIssuerTenderOffer_019f5d1b-9919-7ede-a77c-6bf2e5c75dbf" xlink:href="https://xbrl.sec.gov/dei/2025/dei-2025.xsd#dei_PreCommencementIssuerTenderOffer"/>
    <link:presentationArc order="16" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_019f5d1b-9919-74c4-b96a-97307176dbf9" xlink:to="loc_dei_PreCommencementIssuerTenderOffer_019f5d1b-9919-7ede-a77c-6bf2e5c75dbf" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_Security12bTitle_019f5d1b-9919-7a2b-af8f-a47df9f6b4fa" xlink:href="https://xbrl.sec.gov/dei/2025/dei-2025.xsd#dei_Security12bTitle"/>
    <link:presentationArc order="17" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_019f5d1b-9919-74c4-b96a-97307176dbf9" xlink:to="loc_dei_Security12bTitle_019f5d1b-9919-7a2b-af8f-a47df9f6b4fa" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_TradingSymbol_019f5d1b-9919-7d52-990b-3f5f09f1b4c6" xlink:href="https://xbrl.sec.gov/dei/2025/dei-2025.xsd#dei_TradingSymbol"/>
    <link:presentationArc order="18" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_019f5d1b-9919-74c4-b96a-97307176dbf9" xlink:to="loc_dei_TradingSymbol_019f5d1b-9919-7d52-990b-3f5f09f1b4c6" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_SecurityExchangeName_019f5d1b-9919-7521-a8dc-5450a40fc8ea" xlink:href="https://xbrl.sec.gov/dei/2025/dei-2025.xsd#dei_SecurityExchangeName"/>
    <link:presentationArc order="19" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_019f5d1b-9919-74c4-b96a-97307176dbf9" xlink:to="loc_dei_SecurityExchangeName_019f5d1b-9919-7521-a8dc-5450a40fc8ea" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_EntityEmergingGrowthCompany_019f5d1b-9919-792b-9d9b-c8e96f2cf82a" xlink:href="https://xbrl.sec.gov/dei/2025/dei-2025.xsd#dei_EntityEmergingGrowthCompany"/>
    <link:presentationArc order="20" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_019f5d1b-9919-74c4-b96a-97307176dbf9" xlink:to="loc_dei_EntityEmergingGrowthCompany_019f5d1b-9919-792b-9d9b-c8e96f2cf82a" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_EntityCentralIndexKey_019f5d1b-9919-7c38-9578-dfdc777937af" xlink:href="https://xbrl.sec.gov/dei/2025/dei-2025.xsd#dei_EntityCentralIndexKey"/>
    <link:presentationArc order="21" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_019f5d1b-9919-74c4-b96a-97307176dbf9" xlink:to="loc_dei_EntityCentralIndexKey_019f5d1b-9919-7c38-9578-dfdc777937af" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_AmendmentFlag_019f5d1b-9919-75ca-a209-fd5f9b988867" xlink:href="https://xbrl.sec.gov/dei/2025/dei-2025.xsd#dei_AmendmentFlag"/>
    <link:presentationArc order="22" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_019f5d1b-9919-74c4-b96a-97307176dbf9" xlink:to="loc_dei_AmendmentFlag_019f5d1b-9919-75ca-a209-fd5f9b988867" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
  </link:presentationLink>
</link:linkbase>
